553344
Isopropyl isocyanide
97%
Synonym(s):
2-Isocyanopropane, 2-Propyl isonitrile, Isopropyl isonitrile
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About This Item
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Quality Level
Assay
97%
refractive index
n20/D 1.371 (lit.)
bp
75 °C (lit.)
density
0.733 g/mL at 25 °C (lit.)
functional group
amine
isonitrile
storage temp.
2-8°C
SMILES string
CC(C)[N+]#[C-]
InChI
1S/C4H7N/c1-4(2)5-3/h4H,1-2H3
InChI key
MJZUMMKYWBNKIP-UHFFFAOYSA-N
General description
Isopropyl isocyanide is an alkyl isocyanide.
Application
Isopropyl isocyanide may be used in the preparation of:
- Ugi ligand A2C11I1, which is employed in the solid-phase Ugi synthesis.
- Pentafluorophenyl (PFP) functional monomers, via Passerini reaction.
- Dinuclear copper complex [Cu2(μ-PiPr2bipy)2{μ-CNCH(CH3)2}](PF6)2 [PiPr2bipy = 6-(diisopropylphosphanyl)-2,2′-bipyridine].
- (3E)-(Imino)thiaisoindoline 1,1-dioxide derivative.
- N,N′-diisopropylcarbodiimide (DIC) analog via reaction with propan-2-amine.
- 1-t-butyl-2-isopropyldiaziridinone via reaction with 2-methyl-2-nitrosopropane
- isopropyl isocyanate via reaction with ozone
- 1-phthalimidoazetidines via [1+3]cycloaddition reaction with 1-pththalimidoaziridines
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
69.1 °F - closed cup
Flash Point(C)
20.6 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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