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Supelco

Aldicarb-sulfoxide

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C7H14N2O3S
CAS Number:
Molecular Weight:
206.26
Beilstein:
2212914
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CNC(ON=CC(C)(C)S(C)=O)=O

InChI

1S/C7H14N2O3S/c1-7(2,13(4)11)5-9-12-6(10)8-3/h5H,1-4H3,(H,8,10)

InChI key

BXPMAGSOWXBZHS-UHFFFAOYSA-N

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General description

Aldicarb sulfoxide, cholinesterase inhibitor in insects, is formed from Temik during initial oxidation. It is persistent in soil and is rapidly translocated in plants.

Application

Aldicarb-sulfoxide may be used as a pesticide reference standard for the determination of the analyte in:
  • Fruits and vegetable using solid-phase extraction followed by liquid chromatography-atmospheric pressure chemical ionization mass spectrometry.
  • Water samples by gas chromatography/mass spectrometry (GC-MS) using short capillary columns.
  • Foodstuffs by liquid chromatography-tandem mass spectrometry (LC-MS/MS) using a triple quadrupole analyzer.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 1 Oral - Aquatic Acute 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Liquid chromatography/atmospheric pressure ionization--mass spectrometry in drug metabolism studies.
Kostiainen R, et al.
Journal of Mass Spectrometry : Jms, 38(4), 357-372 (2003)
Application of matrix solid phase dispersion to the determination of imidacloprid, carbaryl, aldicarb, and their main metabolites in honeybees by liquid chromatography-mass spectrometry detection.
Totti S
Talanta, 69(3), 724-729 (2006)
Behavioral Responses of Heterodera rostochiensis Larvae to Aldicarb and its Sulfoxide and Sulfone.
Nelmes AJ.
Journal of Nematology, 2(3), 223-227 (1970)
High performance liquid chromatographic method for the determination of aldicarb sulfoxide in watermelon.
K C Ting et al.
Bulletin of environmental contamination and toxicology, 37(2), 192-198 (1986-08-01)
L R Goldman et al.
Archives of environmental health, 45(3), 141-147 (1990-05-01)
Three outbreaks of food poisoning involving watermelons or cucumbers and caused by the carbamate pesticide aldicarb occurred in California between 1985 and 1988. For each outbreak, and for an outbreak of aldicarb poisoning associated with English cucumbers previously reported in

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