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L6375

Sigma-Aldrich

Lithium sulfate

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≥98.5% (titration)

Synonym(s):

Dilithium sulfate

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About This Item

Linear Formula:
Li2SO4
CAS Number:
10377-48-7
Molecular Weight:
109.94
EC Number:
233-820-4
MDL number:
MFCD00011086
UNSPSC Code:
12352302
PubChem Substance ID:
57654334
NACRES:
NA.23

Quality Level

200

Assay

≥98.5% (titration)

form

powder

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mp

845 °C (lit.)

solubility

absolute ethanol: insoluble(lit.)
acetone: insoluble(lit.)
pyridine: insoluble(lit.)

density

2.22 g/mL at 25 °C (lit.)

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SMILES string

[Li+].[Li+].[O-]S([O-])(=O)=O

InChI

1S/2Li.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2

InChI key

INHCSSUBVCNVSK-UHFFFAOYSA-L

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General description

Lithium sulfate is a white crystalline solid that is soluble in water. The solubility decreases with an increase in temperature. In addition, Lithium sulfate is hygroscopic in nature. It has pyroelectric properties. It has various applications in the fields of lithium-ion batteries, supercapacitors, glass industry, ceramic production, organic synthesis, and manufacture of alloys.
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Application

Lithium sulfate can be used:
  • As a precursor to prepare solid polymer electrolytes.
  • To fabricate lithium borate glasses for energy storage applications.
  • As an electrolyte in self-healing aqueous lithium-ion batteries.
  • As an electrolyte additive in lead acid batteries. The addition of lithium sulfate improves the life cycle and efficiency of acid batteries.
  • As an electrolyte for the production of high energy and power supercapacitors.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Effects of lithium sulfate and zinc sulfate additives on the cycle life and efficiency of lead acid batteries
Nnabundo N Musei, et al.
ACS Omega, 6, 4423-4429 (2021)
Exploring the large voltage range of carbon/carbon supercapacitors in aqueous lithium sulfate electrolyte
Qiang Gao, et al.
Energy & Environmental Science, 5, 9611-9617 (2012)
A self-healing aqueous lithium-ion battery
Yang Zhao, et al.},
Angewandte Chemie (International Edition in English), 55, 14384-14388 (2016)
Possibility of lithium sulfate borate-based glass doping with Ni and Mn ions in energy storage application
Amorntep Montreeuppathum, et al.},
Radiation Physics and Chemistry, 206, 110803-110803 (2023)
Solid polymer electrolytes based on poly(vinylchloride)?lithium sulfate
T.Uma, et al.},
Materials Chemistry and Physics, 90, 239-244 (2005)
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