Skip to Content
Merck
All Photos(1)

Key Documents

06061

Sigma-Aldrich

Allyl phenyl sulfone

purum, ≥98.0% (GC)

Synonym(s):

(2-Propen-1-ylsulfonyl)benzene, (2-Propenylsulfonyl)benzene, (Allylsulfonyl)benzene, Phenyl 2-propenyl sulfone

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
C6H5SO2CH2CH=CH2
CAS Number:
Molecular Weight:
182.24
Beilstein:
1863561
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

purum

Quality Level

Assay

≥98.0% (GC)

form

liquid

refractive index

n20/D 1.548 (lit.)
n20/D 1.548

bp

110-113 °C/0.5 mmHg (lit.)

density

1.189 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C=CCS(=O)(=O)c1ccccc1

InChI

1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2

InChI key

KYPIULIVYSQNNT-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Possible usages of allyl phenyl sulfone:
  • It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
  • It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
  • It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

M. Hirama
Tetrahedron Letters, 22, 1905-1905 (1981)
Proazaphosphatrane P (RNCH2CH2) 3N (R= Me, i?Pr)?Catalyzed Isomerization of Allylaromatics, Allyl Phenyl Sulfide, Allyl Phenyl Sulfone, and bis?Allylmethylene Double Bond?Containing Compounds
Yu Z, et al.
Advanced Synthesis & Catalysis, 348(1?2), 111-117 (2006)
One-Pot Synthesis of Cycloalkane Derivatives using Allyl Phenyl Sulfone and Epoxymesylate.
Miyaoka H, et al.
Tetrahedron, 56(41), 8077-8081 (2000)
D.F. Taber et al.
The Journal of Organic Chemistry, 46, 4817-4817 (1981)
Highly efficient, catalytic bis addition reactions of allyl phenyl sulfone to vinyl sulfones.
Felton G A & Bauld N L
Tetrahedron Letters, 45(25), 4841-4845 (2004)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service