559830

Methyl-2-benzoylbenzoate

97%

• Synonym(s): 2-Benzoylbenzoic acid methyl ester, Methyl o-benzoylbenzoate, o-(Methoxycarbonyl)benzophenone
• Linear Formula: C₆H₅COC₆H₄CO₂CH₃
• CAS Number: 606-28-0
• Molecular Weight: 240.25
• EC Number: 210-112-3
• MDL number: MFCD00017187
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879647
• NACRES: NA.22

Properties

• Assay: 97%
• form: solid
• mp: 48-53 °C (lit.)
• functional group: ester; ketone; phenyl
• SMILES string: COC(=O)c1ccccc1C(=O)c2ccccc2
• InChI: 1S/C15H12O3/c1-18-15(17)13-10-6-5-9-12(13)14(16)11-7-3-2-4-8-11/h2-10H,1H3
• InChI key: NQSMEZJWJJVYOI-UHFFFAOYSA-N

Description

General description

Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate.

• It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst.
• Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.
• Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.

Safety Information

• Pictograms: GHS09
• Signal Word: Warning
• Hazard Statements: H410
• Precautionary Statements: P273 - P391 - P501
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves