Skip to Content
Merck
All Photos(1)

Documents

438936

Sigma-Aldrich

1,4-Bis(trimethylsilyl)benzene

96%

Synonym(s):

p-Phenylenebis(trimethylsilane)

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
C6H4[Si(CH3)3]2
CAS Number:
13183-70-5
Molecular Weight:
222.47
Beilstein:
1867055
MDL number:
MFCD00015592
UNSPSC Code:
12352100
PubChem Substance ID:
24867483
NACRES:
NA.22

Assay

96%

form

solid

bp

194 °C/742 mmHg (lit.)

mp

91-94 °C (lit.)

SMILES string

C[Si](C)(C)c1ccc(cc1)[Si](C)(C)C

InChI

1S/C12H22Si2/c1-13(2,3)11-7-9-12(10-8-11)14(4,5)6/h7-10H,1-6H3

InChI key

NVRBTKMAZQNKPX-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

1,4-Bis(trimethylsilyl)benzene (TMSB) can be used:
  • As a precursor for developing silicon carbide coating using plasma-assisted chemical vapor deposition (CVD) process.
  • As a secondary standard in quantitative NMR (qNMR) spectroscopy.
  • As an internal standard for quantitation of small organic molecules in DMSO-d6 solution by 1H NMR spectroscopy.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

347.0 °F - closed cup

Flash Point(C)

175 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

Hexamethylbenzene 99%

Sigma-Aldrich

322377

Hexamethylbenzene

Characterization of small combinatorial chemistry libraries by 1H NMR. Quantitation with a convenient and novel internal standard
Pinciroli V, et al.
Journal of Combinatorial Chemistry, 3(5), 434-440 (2001)
Synthesis of 1, 4-dihydropyrrolo [3, 2-b] pyrrole.
Kumagai T, et al.
Tetrahedron Letters, 25(49), 5669-5672 (1984)
Role of vapor pressure of 1, 4-bis (trimethylsilyl) benzene in developing silicon carbide thin film using a plasma-assisted liquid injection chemical vapor deposition process
Selvakumar J, et al.
Surface and Coatings Technology, 205(11), 3493-3498 (2011)
Use and qualification of primary and secondary standards employed in quantitative 1H NMR spectroscopy of pharmaceuticals
Rundlof T, et al.
Journal of Pharmaceutical and Biomedical Analysis, 93(11), 111-117 (2014)
Torgny Rundlöf et al.
Journal of pharmaceutical and biomedical analysis, 93, 111-117 (2013-11-12)
Standards are required in quantitative NMR (qNMR) to obtain accurate and precise results. In this study acetanilide was established and used as a primary standard. Six other chemicals were selected as secondary standards: 3,4,5-trichloropyridine, dimethylterephthalate, maleic acid, 3-sulfolene, 1,4-bis(trimethylsilyl)benzene, and

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service