282235

Methylmagnesium bromide solution

1.4 M in THF: toluene (1:3)

• Synonym(s): Bromomethylmagnesium
• Linear Formula: CH₃MgBr
• CAS Number: 75-16-1
• Molecular Weight: 119.24
• Beilstein: 3535220
• MDL number: MFCD00000041
• UNSPSC Code: 12352111
• PubChem Substance ID: 24857032
• NACRES: NA.22

Properties

• Quality Level: 200
• reaction suitability: reaction type: Grignard Reaction
• concentration: 1.4 M in THF: toluene (1:3)
• density: 1.018 g/mL at 25 °C
• SMILES string: C[Mg]Br
• InChI: 1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1
• InChI key: AVFUHBJCUUTGCD-UHFFFAOYSA-M

Description

Application

Methylmagnesium bromide is generally used as a Grignard reagent for C-C bond formation by reacting with the carbonyl groups of aldehydes and ketones.

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H260,H304,H314,H336,H351,H361d,H373,H412
• Precautionary Statements: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
• Target Organs: Central nervous system, Respiratory system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 1.4 °F - closed cup
• Flash Point(C): -17 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves