The 25 mL size is packaged in 35 mL narrow mouth amber glass bottle with a PTFE lined Red Polypropylene cap. Please see the representative image below.
179728
Super-Hydride® solution
1.0 M lithium triethylborohydride in THF
Synonym(s):
Lithium triethylborohydride solution
Sign Into View Organizational & Contract Pricing
All Photos(2)
About This Item
Linear Formula:
Li(C2H5)3BH
CAS Number:
Molecular Weight:
105.94
Beilstein:
4151240
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.
Recommended Products
form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M lithium triethylborohydride in THF
density
0.892 g/mL at 25 °C
SMILES string
[Li+].[H][B-](CC)(CC)CC
InChI
1S/C6H16B.Li/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
InChI key
WCJAYABJWDIZAJ-UHFFFAOYSA-N
Looking for similar products? Visit Product Comparison Guide
Related Categories
General description
Application
LiTEBH can be used as a reagent:
- To reduce alkyl halides to alkanes via dehydrogenation reactions.[1][3]
- For the selective reduction of epoxides to Markovnikov alcohols.[4]
- To reduce tosylates or mesylates primary alcohols to hydrocarbons.[1]
- For reductive cyclization reactions for the preparation of useful intermediates.[5]
- In the synthesis of hepta(manno-3-deoxy-6-O-t-butyldimethylsilyl)-β-cyclodextrin by reduction of hepta(manno-2,3-anhydro-6-O-t-butyldimethylsilyl)-β-cyclodextrin.[6]
- For hydrodefluorination of C-F bonds using Ni catalyst.[1]
- To prepare alkynyl alcohols from cleavage of cyclic keto-vinyl triflates.[7]
- In the stereoselective reduction of bicyclic imides,[8] isoquinolines, and pyridines.[9]
- To prepare tungsten and molybdenum hydride complexes.[10]
Packaging
Legal Information
Super-Hydride is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Choose from one of the most recent versions:
Certificates of Analysis (COA)
Lot/Batch Number
Don't see the Right Version?
If you require a particular version, you can look up a specific certificate by the Lot or Batch number.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Customers Also Viewed
Sci. Synth., 2, 13-89 (2003)
Reduction of isoquinoline and pyridine-containing heterocycles with lithium triethylborohydride (Super-Hydride)
Blough BE and Carroll FI
Tetrahedron Letters, 34(45), 7239-7242 (1993)
Regio-and stereoselective reduction of bicyclic imides for the asymmetric synthesis of highly substituted pyrrolidines
Deprez P, et al.
Tetrahedron, 49(18), 3781-3792 (1993)
Selective reductions. 32. Structural effects on the reduction of epoxides by lithium triethylborohydride. A kinetic study
Brown HC, et al.
The Journal of Organic Chemistry, 48(18), 3091-3096 (1983)
Synthesis of the first per (3-deoxy)-cyclooligosaccharide: hepta (manno-3-deoxy-6-Ot-butyldimethylsilyl)-β-cyclodextrin
Kelly DR and Mishal AK
Tetrahedron Asymmetry, 10(18), 3627-3648 (1999)
-
超水素化溶液のの購入を検討しています。25MLx4本入りパッケージについて、試料容器はどのようになっているか教えていただけますでしょうか。具体的には、試料容器の形態（アンプル、蓋つき瓶等）、サイズについての情報が知りたいです。よろしくお願い足します。
1 answer
Active Filters
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service
