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76778

Supelco

Methyl acrylate

analytical standard

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About This Item

Linear Formula:
CH2=CHCOOCH3
CAS Number:
Molecular Weight:
86.09
Beilstein:
605396
EC Number:
MDL number:
UNSPSC Code:
85151701
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

3 (vs air)

vapor pressure

67.5 mmHg ( 20 °C)

Assay

≥99.5% (GC)

autoignition temp.

874 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.0015% hydroquinone monomethyl ether as stabilizer

expl. lim.

14.5 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.402 (lit.)
n20/D 1.403

bp

80 °C (lit.)

mp

−75 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

application(s)

environmental
petroleum

format

neat

SMILES string

COC(=O)C=C

InChI

1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3

InChI key

BAPJBEWLBFYGME-UHFFFAOYSA-N

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General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Application

Methyl acrylate can undergo transesterification reaction with 1-butanol under thermal conditions in the presence of hydrochloric acid to yield butyl acrylate as the major product.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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Pictograms

FlameSkull and crossbones

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

27.0 °F - closed cup

Flash Point(C)

-2.8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Organic Chemistry (2008)
Xin Liu et al.
Journal of hazardous materials, 175(1-3), 1014-1021 (2009-11-27)
Porous acrylonitrile (AN)/methyl acrylate (MA) copolymer beads were prepared by suspended emulsion polymerization. The cyano groups in AN/MA copolymer beads were converted to amidoxime (AO) groups by reaction with hydroxylamine hydrochloride (NH(2)OH.HCl) to remove metal ions in aqueous solution. The
Nicky Chan et al.
Macromolecular rapid communications, 32(7), 604-609 (2011-03-26)
The use of copper tubing as both the reactor and as a catalyst source is demonstrated for continuous controlled radical polymerization of methyl acrylate at ambient temperature and at low solvent content of 30%. The high surface area provided by
Transformation of nickelalactones to methyl acrylate: on the way to a catalytic conversion of carbon dioxide.
S Y Tina Lee et al.
ChemSusChem, 4(9), 1275-1279 (2011-09-17)
Cláudio G L Junior et al.
Bioorganic chemistry, 38(6), 279-284 (2010-09-22)
Sixteen aromatic Morita-Baylis-Hillman adducts (MBHA) 1-16 were efficiently synthesized in a one step Morita-Baylis-Hillman reaction (MBHR) involving commercial aldehydes with methyl acrylate or acrylonitrile (81-100% yields) without the formation of side products on DABCO catalysis and at low temperature (0°C).

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