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Sigma-Aldrich

2-Bromoethyl methyl ether

Synonym(s):

1-Bromo-2-methoxyethane

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About This Item

Linear Formula:
BrCH2CH2OCH3
CAS Number:
6482-24-2
Molecular Weight:
138.99
EC Number:
229-339-4
MDL number:
MFCD00000236
UNSPSC Code:
12352100
PubChem Substance ID:
24854144
NACRES:
NA.22

form

liquid

refractive index

n20/D 1.447 (lit.)

bp

40-41 °C/66 mmHg (lit.)

solubility

water: soluble 14.4 g/L at 25 °C

density

1.479 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

COCCBr

InChI

1S/C3H7BrO/c1-5-3-2-4/h2-3H2,1H3

InChI key

YZUPZGFPHUVJKC-UHFFFAOYSA-N

General description

Kinetics of potassium iodide exchange reaction with 2-bromoethyl methyl ether in acetone at 15 and 25°C has been investigated.

Application

2-Bromoethyl methyl ether has been used as starting reagent in the synthesis of 1-bromo-4-(2-methoxyethoxy)benzene and 1-bromo-4-[(2-methoxyethoxy)methyl]benzene.

Pictograms

FlameSkull and crossbones
GHS02,GHS06

Signal Word

Danger

Hazard Statements

H226,H301,H315,H319,H335

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

82.4 °F - closed cup

Flash Point(C)

28 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The Iodide Ion Exchange Reaction with 2-Haloethyl Alkyl Ethers and n-Butyl Bromide1.
Tutwiler FB and McKee RL.
Journal of the American Chemical Society, 76(24), 6342-6344 (1954)
Novel water-soluble organosilane compounds as a radical reducing agent in aqueous media.
Yamazaki O, et al.
Bulletin of the Chemical Society of Japan, 70, 2519-2523 (1997)
Alex R Neale et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(15), 2040-2057 (2017-05-19)
A series of hydrophobic room temperature ionic liquids (ILs) based on ethereal functionalised pyrrolidinium, piperidinium and azepanium cations bearing the bis[(trifluoromethyl)sulfonyl]imide, [TFSI]
Forrest S Gittleson et al.
Physical chemistry chemical physics : PCCP, 21(31), 17176-17189 (2019-07-26)
Ionic liquids are a unique class of materials with several potential applications in electrochemical energy storage. When used in electrolytes, these highly coordinating solvents can influence device performance through their high viscosities and strong solvation behaviors. In this work, we
Hancheng Zhou et al.
Molecules (Basel, Switzerland), 24(17) (2019-08-30)
Tunable properties prompt the development of different "tailor-made" functional ionic liquids (FILs) for specific tasks. FILs with an ether group are good solvents for many organic compounds and enzymatic reactions. However, ionic composition influences the solubility by affecting the physiochemical
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