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366374

Sigma-Aldrich

Zinc chloride solution

0.5 M in THF

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
MDL number:
MFCD00011295
UNSPSC Code:
12352302
PubChem Substance ID:
329755428
NACRES:
NA.55

form

liquid

Quality Level

100

concentration

0.5 M in THF
470-600 mmol/L (silver nitrate titration)

density

0.948 g/mL at 25 °C

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Certificates of Analysis (COA)

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Thin-layer electrochemistry of ferrocenylbenzene derivatives: Intramolecular electronic communication.
Wang MCP, et al.
Electrochimica Acta, 53(26), 7720-7725 (2008)
Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
Molouk Beiromvand et al.
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Certain zoonotic parasites are enteropathogens in dogs that cause serious human disease such as cystic echinococcosis, human alveolar echinococcosis, visceral larva migrans, and ocular larva migrans. This study investigated the prevalence of intestinal parasites in dogs in the Chenaran County
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Plant science : an international journal of experimental plant biology, 198, 7-16 (2012-12-04)
Manganese stabilizing protein (MSP) is an important component of the Photosystem II (PSII) oxygen evolving complex. In our previous work, transgenic potato plants with reduced expression of MSP (MSP-As) were developed and their physiological and biochemical responses were studied. In
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