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31445

Sigma-Aldrich

Sodium peroxide

puriss. p.a., ACS reagent, reag. ISO, ≥95%

Synonym(s):

Sodium superoxide

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About This Item

Empirical Formula (Hill Notation):
Na2O2
CAS Number:
1313-60-6
Molecular Weight:
77.98
EC Number:
215-209-4
MDL number:
MFCD00003497
UNSPSC Code:
12352304
PubChem Substance ID:
329753769
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

100

Agency

reag. ISO

Assay

≥95%

form

powder

impurities

≤0.002% heavy metals (as Pb)
≤0.003% total nitrogen (N)

pH

12.8 (20 °C, 100 g/L)

mp

460 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤20 mg/kg
phosphate (PO43-): ≤5 mg/kg
sulfate (SO42-): ≤10 mg/kg

cation traces

Al: ≤10 mg/kg
Fe: ≤20 mg/kg

SMILES string

[Na+].[Na+].[O-][O-]

InChI

1S/2Na.O2/c;;1-2/q2*+1;-2

InChI key

PFUVRDFDKPNGAV-UHFFFAOYSA-N

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General description

Sodium peroxide (Sodium superoxide) has been synthesized by the matrix reaction of sodium atoms and oxygen molecules at high dilution in argon. Its IR spectral studies have been reported.

Application

Sodium peroxide may be used for the isotope dilution inductively coupled plasma mass spectrometric quantification of Ru, Pd, Ir, Pt and rare earth elements (such as Y, Th, Zr, Hf, Nb and Ta) in various geological samples.

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H271,H314

Hazard Classifications

Ox. Sol. 1 - Skin Corr. 1A

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Infrared spectra and bonding in the sodium superoxide and sodium peroxide molecules.
Andrews L.
The Journal of Physical Chemistry, 73(11), 3922-3928 (1969)
Determination of platinum, palladium, ruthenium and iridium in geological samples by isotope dilution inductively coupled plasma mass spectrometry using a sodium peroxide fusion and tellurium coprecipitation
Enzweiler J, et al.
Analyst, 120(5), 1391-1396 (1995)
Christine Sedgley
Journal of the history of dentistry, 52(2), 61-65 (2004-08-06)
The concept of the germ theory of disease combined with the development of dentistry during the latter half of the 19th century had a direct effect on the practice of endodontics. The significance of root canal irrigation to endodontics strengthened
[Rapid ultraviolet-absorption photometric determination of the protein content of aqueous extracts in the microgram area using Na2O2].
B Löhrke
Zeitschrift fur medizinische Laboratoriumsdiagnostik, 27(2), 92-95 (1986-01-01)
K J Sreeram et al.
Journal of environmental monitoring : JEM, 3(5), 526-530 (2001-11-07)
The processing of chromite ore is associated with the generation of large quantities of solid wastes containing chromium, which have been disposed of as landfill for many years. The mobilization and operational speciation of chromium contained in soils contaminated with
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