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Key Documents

221287

Sigma-Aldrich

Manganese(II) sulfate monohydrate

ACS reagent, ≥98%

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About This Item

Linear Formula:
MnSO4 · H2O
CAS Number:
Molecular Weight:
169.02
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent

Quality Level

Assay

≥98%

form

powder

impurities

MnO4- reducers, passes test
≤0.01% insolubles

loss

10.0-12.0% loss on ignition

pH

3-3.5 (20 °C, 50 g/L)

anion traces

chloride (Cl-): ≤0.005%

cation traces

Ca: ≤0.005%
Fe: ≤0.002%
K: ≤0.01%
Mg: ≤0.005%
Na: ≤0.05%
Ni: ≤0.02%
Zn: ≤0.005%
heavy metals: ≤0.002% (by ICP)

storage temp.

2-8°C

SMILES string

O.[Mn++].[O-]S([O-])(=O)=O

InChI

1S/Mn.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+2;;/p-2

InChI key

ISPYRSDWRDQNSW-UHFFFAOYSA-L

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Application

Manganese(II) sulfate monohydrate can undergo metathesis reaction with different chromate, molybdate and tungstate salts in aqueous medium to form corresponding hydrated manganese group 6 metal oxides.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 Inhalation

Target Organs

Brain

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Preliminary screening of purification processes of liquor leach solutions obtained from reductive leaching of low-grade manganese ores.
Pagnanelli F, et al.
Hydrometallurgy, 71(3), 319-327 (2004)
Measurement of net high-affinity urea uptake in maize plants.
Zanin L, et al.
Bio-protocol, 5, e1490-e1490 (2015)
Aqueous crystallization of manganese (II) group 6 metal oxides.
Meehae J, et al.
Chemistry of Materials, 13(2), 519-525 (2001)
Extraction and preconcentration of manganese (II) from biological fluids (water, milk and blood serum) using supported liquid membrane and membrane probe methods.
Soko L, et al.
Analytica Chimica Acta, 485(1), 25-35 (2003)
Zhehui Weng et al.
Inorganic chemistry, 48(18), 8703-8708 (2009-08-25)
A new glycine-templated manganese(II) sulfate, (C(2)NO(2)H(5))MnSO(4) (1), has been solvothermally synthesized and characterized crystallographically and magnetically. Crystal data for 1: monoclinic, space group P2(1)/m, a = 4.8884(10) A, b = 7.8676(14) A, c = 8.0252(15) A, beta = 106.524(2) degrees

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