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46447

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Trifloxystrobin

PESTANAL®, analytical standard

Synonym(s):

Methyl (E)-α-methoxyimino-2-[(E)-1-(3-trifluoromethylphenyl)ethylidenaminooxymethyl]phenylacetate

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About This Item

Empirical Formula (Hill Notation):
C20H19F3N2O4
CAS Number:
Molecular Weight:
408.37
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CO\N=C(\C(=O)OC)c1ccccc1CO\N=C(/C)c2cccc(c2)C(F)(F)F

InChI

1S/C20H19F3N2O4/c1-13(14-8-6-9-16(11-14)20(21,22)23)24-29-12-15-7-4-5-10-17(15)18(25-28-3)19(26)27-2/h4-11H,12H2,1-3H3/b24-13+,25-18+

InChI key

ONCZDRURRATYFI-TVJDWZFNSA-N

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General description

Trifloxystrobin is classified under the group of new strobilurin fungicides applied in viticulture for the control of downy (Plasmopara viticola) and powdery (Uncinula necator) mildews. Its mode of action involves the inhibition of the mitochondrial respiration by means of its binding at the Qo site of cytochrome b, present in the inner mitochondrial membrane of the fungi.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Trifloxystrobin may be used as an analytical reference standard for the determination of the analyte in wine, fruits and vegetables, and rice and soil samples by various chromatographic techniques.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Lact. - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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William H Mimbs et al.
Chemosphere, 159, 275-281 (2016-06-15)
Wetlands in the Rainwater Basin (RWB) of Nebraska are commonly in close proximity to or embedded within row-crop agriculture. Several fungicides and bifenthrin are applied aerially to corn throughout the RWB during tassel stage. Thus, aerial spray drift and runoff
Validation and global uncertainty of a liquid chromatographic with diode array detection method for the screening of azoxystrobin, kresoxim-methyl, trifloxystrobin, famoxadone, pyraclostrobin and fenamidone in grapes and wine.
de Melo Abreu S, et al.
Analytica Chimica Acta, 573, 291-297 (2006)
Celeste Azpiazu et al.
Insects, 11(1) (2020-01-24)
Planting flower strips adjacent to crops is among the habitat-management practices employed to offer alternative floral resources to pollinators. However, more information is needed to understand their potential spill-over of pollinators on nearby insect-pollinated crops. Over the course of two
Yoonjeong Jang et al.
The Journal of toxicological sciences, 41(6), 731-737 (2016-11-18)
Trifloxystrobin is a strobilurin class fungicide, the mode of action of which is to block the mitochondrial electron transport chain and inhibit energy production in fungi. Although adverse effects have been reported by occupational or environmental exposure of fungicides, the
Suzane Rickes da Luz et al.
Food chemistry, 220, 510-516 (2016-11-20)
Wheat (Triticum aestivum) is an annual crop, cultivated in the winter and spring and susceptible to several pathogens, especially fungi, which are managed with fungicides. It is also one of the most consumed cereals, and can be contaminated by mycotoxins

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