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B35407

Sigma-Aldrich

2,2′-Biquinoline

98%

Synonym(s):

2,2′-Diquinolyl, Cuproin

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About This Item

Empirical Formula (Hill Notation):
C18H12N2
CAS Number:
119-91-5
Molecular Weight:
256.30
Beilstein:
187259
EC Number:
204-357-5
MDL number:
MFCD00006740
UNSPSC Code:
12352100
PubChem Substance ID:
24891725
NACRES:
NA.22

Quality Level

200

Assay

98%

form

powder

mp

192-195 °C (lit.)

SMILES string

c1ccc2nc(ccc2c1)-c3ccc4ccccc4n3

InChI

1S/C18H12N2/c1-3-7-15-13(5-1)9-11-17(19-15)18-12-10-14-6-2-4-8-16(14)20-18/h1-12H

InChI key

WPTCSQBWLUUYDV-UHFFFAOYSA-N

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Application

2,2′-Biquinoline can be utilized as a ligand in the synthesis of heteroleptic Cu(I) complexes for light-emitting diodes(LED) and cationic iridium(III) complexes as phosphorescent dyes for live-cell imaging.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Novel Heteroleptic CuI Complexes with Tunable Emission Color for Efficient Phosphorescent Light-Emitting Diodes
Zhang Q, et al.
Advances in Functional Materials, 17(15), 2983-2990 (2007)
Cationic iridium (III) complexes with tunable emission color as phosphorescent dyes for live cell imaging
Zhao Q, et al.
Organometallics, 29(5), 1085-1091 (2010)
J Chowdhury et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(11), 2107-2115 (2000-11-01)
Surface enhanced Raman scattering (SERS) in silver sol and normal Raman spectra in the bulk and in solution of 2,2' biquinoline (BQ) molecule have been investigated. The observed Raman bands along with their corresponding FTIR bands have been assigned based
Daniela Pucci et al.
Dalton transactions (Cambridge, England : 2003), 40(17), 4614-4622 (2011-04-01)
The synthesis and characterization of a series of 2,2'-biquinolines differently substituted in the 4,4'-position and their corresponding silver(I) derivatives obtained through reaction with silver triflate in a 1 : 1 stoichiometric ratio are reported. In order to perform a systematic
Leszek Pazderski et al.
Magnetic resonance in chemistry : MRC, 45(12), 1059-1071 (2007-11-30)
1H, 13C, and 15N NMR studies of platinide(II) (M=Pd, Pt) chloride complexes with quinolines (L=quinoline-quin, or isoquinoline-isoquin; LL=2,2'-biquinoline-bquin), having the general formulae trans-/cis-[ML2Cl2] and [M(LL)Cl2], were performed and the respective chemical shifts (delta1H, delta13C, delta15N) reported. 1H coordination shifts of
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