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569364

Sigma-Aldrich

9,9-Dioctylfluorene-2,7-diboronic acid

96%

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About This Item

Linear Formula:
(HO)2BC(C6H3C(C8H17)2C6H3B(OH)2
CAS Number:
258865-48-4
Molecular Weight:
478.28
MDL number:
MFCD03701608
UNSPSC Code:
12352103
PubChem Substance ID:
24880497
NACRES:
NA.22

Quality Level

100

Assay

96%

mp

158-162 °C (lit.)

SMILES string

CCCCCCCCC1(CCCCCCCC)c2cc(ccc2-c3ccc(cc13)B(O)O)B(O)O

InChI

1S/C29H44B2O4/c1-3-5-7-9-11-13-19-29(20-14-12-10-8-6-4-2)27-21-23(30(32)33)15-17-25(27)26-18-16-24(31(34)35)22-28(26)29/h15-18,21-22,32-35H,3-14,19-20H2,1-2H3

InChI key

HURJMQMZDPOUOU-UHFFFAOYSA-N

Application

9,9-Dioctylfluorene-2,7-diboronic acid can be used as a reactant to synthesize hyperbranched conjugated conductive copolymers by Pd-catalyzed Suzuki-Miyaura cross coupling (SMC) copolymerization reaction with different dibromoarenes.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBF1944V
SHBD9568V
SHBB0646V
SHBB0645V
71496DM

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Synthesis of hyperbranched conjugated copolymers containing triphenylamine and fluorene or thiophene moieties
Grigoras M and Stafie L
High Performance Polymers, 21(3), 304-314 (2009)
Unexpected structural defects in a main-chain conjugated polymer synthesized through Suzuki-Miyaura cross coupling polymerization
Yuan Y, et al.
Polymer, 226, 123769-123769 (2021)
Conjugated copolymers bearing 2, 7-dithienylphenanthrene-9, 10-dialkoxy units: highly soluble and stable deep-blue emissive materials
Baig N, et al.
New. J. Chem., 44(22), 9557-9564 (2020)
Zhiwei Chu et al.
Sensors (Basel, Switzerland), 18(5) (2018-05-16)
An aggregation-caused quenching (ACQ)-active polymer (PF), an aggregation-induced emission (AIE)-active polymer (PFTPE) and an aggregation-enhanced emission (AEE)-active polymer (PTTPE) were synthesized by tetraphenylethane (TPE), fluorene and thiophene moieties. Polyurethane (PU) foams modified by PF, PFTPE and PTTPE, namely PU-PF, PU-PFTPE

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