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494070

Sigma-Aldrich

6,6′′-Dibromo-2,2′:6′,2′′-terpyridine

90%

Synonym(s):

6,6′′-Dibromo-2,2′:6′,2′′-terpyridine

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About This Item

Empirical Formula (Hill Notation):
C15H9Br2N3
CAS Number:
100366-66-3
Molecular Weight:
391.06
MDL number:
MFCD01863557
UNSPSC Code:
12352100
PubChem Substance ID:
24872873
NACRES:
NA.22

Quality Level

100

Assay

90%

mp

257-263 °C (lit.)

SMILES string

Brc1cccc(n1)-c2cccc(n2)-c3cccc(Br)n3

InChI

1S/C15H9Br2N3/c16-14-8-2-6-12(19-14)10-4-1-5-11(18-10)13-7-3-9-15(17)20-13/h1-9H

InChI key

PYMBATDYUCQLBC-UHFFFAOYSA-N

General description

6,6′′-Dibromo-2,2′:6′,2′′-terpyridine is a substituted terpyridine that can be synthesized from 2,6-dibromopyridine.

Application

6,6′′-Dibromo-2,2′:6′,2′′-terpyridine may be used in the synthesis of a novel disubstituted terpyridine ligand.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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A Novel One-Pot Synthesis of 6,6''-Dibromo-2,2':6'2''-terpyridine.
Uchida Y, et al.
ChemInform, 26(50) (1995)
Kogularamanan Suntharalingam et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(47), 15133-15141 (2012-10-13)
A new disubstituted terpyridine ligand and the corresponding tri-copper(II) complex have been prepared and characterised. The binding affinity and binding mode of this tri-copper complex (as well as the previously reported mono- and di-copper analogues) towards duplex DNA were determined
Lingjing Chen et al.
Dalton transactions (Cambridge, England : 2003), 48(26), 9596-9602 (2019-02-20)
A new pentadentate quinoline-pyridine ligand and its iron (1), cobalt (2) and nickel (3) complexes have been synthesized and characterized. The iron complex exhibits excellent photocatalytic activity towards CO2-to-CO conversion with a TON(CO) of 544 and a selectivity of 99.3%

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