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473804

Sigma-Aldrich

2-Bromophenylboronic acid

greener alternative

≥95.0%

Synonym(s):

o-Bromophenylboronic acid

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About This Item

Linear Formula:
BrC6H4B(OH)2
CAS Number:
Molecular Weight:
200.83
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥95.0%

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

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Greener Alternative Product

mp

113 °C (lit.)

greener alternative category

SMILES string

OB(O)c1ccccc1Br

InChI

1S/C6H6BBrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4,9-10H

InChI key

PLVCYMZAEQRYHJ-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

Other Notes

Contains varying amounts of anhydride

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Pictograms

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Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


Certificates of Analysis (COA)

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Yae In Cho et al.
Inorganic chemistry, 58(19), 12689-12699 (2019-09-10)
We report syntheses and H2 activation involving model complexes of mono-iron hydrogenase (Hmd) derived from acyl-containing pincer ligand precursors bearing thioether (CNS

Articles

We are proud to offer a number of products used in catalytic amidation technology.

We are proud to offer a number of products used in catalytic amidation technology.

We are proud to offer a number of products used in catalytic amidation technology.

We are proud to offer a number of products used in catalytic amidation technology.

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