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Merck

420697

Sigma-Aldrich

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine

96%

Synonym(s):

N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine, N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine, Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine

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About This Item

Linear Formula:
C6H5CH2N(CH2OCH3)CH2Si(CH3)3
CAS Number:
Molecular Weight:
237.41
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

Assay

96%

form

liquid

refractive index

n20/D 1.492 (lit.)

bp

76 °C/0.3 mmHg (lit.)

density

0.928 g/mL at 25 °C (lit.)

functional group

amine
ether
phenyl

SMILES string

COCN(Cc1ccccc1)C[Si](C)(C)C

InChI

1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3

InChI key

RPZAAFUKDPKTKP-UHFFFAOYSA-N

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This Item
HPA004877SAB5700809SAB4501486
conjugate

unconjugated

conjugate

unconjugated

conjugate

-

conjugate

unconjugated

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

antibody form

affinity isolated antibody

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Prestige Antibodies® Powered by Atlas Antibodies

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Prestige Antibodies® Powered by Atlas Antibodies

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-

product line

-

clone

polyclonal

clone

polyclonal

clone

polyclonal

clone

polyclonal

Gene Information

human ... ICAM1(3383)

Gene Information

human ... ICAM1(3383)

Gene Information

human ... ICAM1(3383)

Gene Information

human ... ICAM1(3383)

Application

Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.[1]
Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.[2]

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

150.8 °F - closed cup

Flash Point(C)

66 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Find documentation for the products that you have recently purchased in the Document Library.

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Kotian, Pravin L.; et al.
Organic Process Research & Development, 9(2), 193-197 (2005)
Synthesis, 2646-2646 (2006)

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