227307

Sodium triethylborohydride solution

1.0 M in toluene

• Synonym(s): Sodium triethylborate, Sodium triethylhydridoborate, Sodium triethylhydroborate
• Linear Formula: (C₂H₅)₃NaBH
• CAS Number: 17979-81-6
• Molecular Weight: 121.99
• Beilstein: 4151241
• MDL number: MFCD00011704
• UNSPSC Code: 12352000
• PubChem Substance ID: 24853623
• NACRES: NA.22

Properties

• form: liquid
• Quality Level: 100
• reaction suitability: reagent type: reductant
• concentration: 1.0 M in toluene
• density: 0.866 g/mL at 25 °C
• SMILES string: [Na+].[H][B-](CC)(CC)CC
• InChI: 1S/C6H16B.Na/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
• InChI key: YDTZLEUIYNMRLQ-UHFFFAOYSA-N

Description

Application

Reactant for:

• Preparation of alcohols by hydrogenation of ketones catalyzed by an iron pincer complex
• Preparation of alkali metal boron monohydride complexes
• Coordinative substitution reactions
• Ligand exchange reactions

• Hydridic reagent

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H261,H304,H314,H336,H361d,H373,H412
• Precautionary Statements: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2
• Target Organs: Central nervous system, Respiratory system
• Supplementary Hazards: EUH014
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 44.6 °F - closed cup
• Flash Point(C): 7 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves