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218227

Sigma-Aldrich

Cesium hydrogencarbonate

99.9%

Synonym(s):

Cesium bicarbonate

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About This Item

Linear Formula:
CsHCO3
CAS Number:
29703-01-3
Molecular Weight:
193.92
EC Number:
249-784-8
MDL number:
MFCD00010961
UNSPSC Code:
12352302
PubChem Substance ID:
24853052
NACRES:
NA.22

Quality Level

100

Assay

99.9%

form

solid

SMILES string

[Cs+].OC([O-])=O

InChI

1S/CH2O3.Cs/c2-1(3)4;/h(H2,2,3,4);/q;+1/p-1

InChI key

ZMCUDHNSHCRDBT-UHFFFAOYSA-M

General description

Cesium hydrogencarbonate is used as a source of bicarbonate ions.

Application

Cesium hydrogencarbonate can be used as a base:
  • In the Ni-catalyzed hydroarylation of unactivated alkenes with arylboronic acids to synthesize arylated alkanes.
  • To synthesize 5-phenylthiazolamines by coupling thiourea with phenylacetones, phenylacetophenones, and β-tetralone in the presence of CBrCl3.
  • In the Pd-catalyzed hydroxycarbonylation of aryl halides.
  • In the regioselective alkylation of 2,4-dihydroxybenzyaldehydes and 2,4-dihydroxyacetophenones using alkyl halides to synthesize 4-alkylated products.
It can also be used as a catalyst for the:
  • Etherification of glycerol to oligomers.
  • Acetylation of primary alcohols and phenols to acetates using acetic anhydride.

Pictograms

Health hazardCorrosion
GHS08,GHS05

Signal Word

Danger

Hazard Statements

H318,H361f,H373

Hazard Classifications

Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral

Target Organs

Kidney,Adrenal gland,Testes

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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