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646075

Sigma-Aldrich

p-Tolylmagnesium bromide solution

0.5 M in diethyl ether

Synonym(s):

4-Methylphenylmagnesium bromide

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About This Item

Linear Formula:
CH3C6H4MgBr
CAS Number:
4294-57-9
Molecular Weight:
195.34
Beilstein:
636491
MDL number:
MFCD00000040
UNSPSC Code:
12352103
PubChem Substance ID:
24883432
NACRES:
NA.22

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in diethyl ether

SMILES string

Cc1ccc([Mg]Br)cc1

InChI

1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1

InChI key

ZRJNGFJIBZKXTP-UHFFFAOYSA-M

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Signal Word

Danger

Hazard Statements

H224,H302,H314,H336

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-40.0 °F - closed cup - Solvent

Flash Point(C)

-40 °C - closed cup - Solvent

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Derek E Williams et al.
Journal of the American Chemical Society, 140(24), 7611-7622 (2018-05-29)
Stimuli-responsive materials are vital for addressing emerging demands in the advanced technology sector as well as current industrial challenges. Here, we report for the first time that coordinative integration of photoresponsive building blocks possessing photochromic spiropyran and diarylethene moieties within
Ekaterina A Dolgopolova et al.
Journal of the American Chemical Society, 141(13), 5350-5358 (2019-03-07)
Electronic structure modulation of metal-organic frameworks (MOFs) through the connection of linker "wires" as a function of an external stimulus is reported for the first time. The established correlation between MOF electronic properties and photoisomerization kinetics as well as changes

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