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518883

Sigma-Aldrich

Dichlorodiphenoxymethane

Synonym(s):

Phosgene diphenyl acetal

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About This Item

Linear Formula:
(C6H5O)2CCl2
CAS Number:
4885-03-4
Molecular Weight:
269.12
MDL number:
MFCD00087870
UNSPSC Code:
12352100
PubChem Substance ID:
24874053
NACRES:
NA.22

mp

39-44 °C (lit.)

SMILES string

ClC(Cl)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C13H10Cl2O2/c14-13(15,16-11-7-3-1-4-8-11)17-12-9-5-2-6-10-12/h1-10H

InChI key

TVIUSKXXXZSVJU-UHFFFAOYSA-N

Application

Reactant for:
  • Cyclocondensation of aminophenols and amines
  • Preparation of LIM-Kinase 2 inhibitors for the treatment of ocular hypertension

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBR7279V
BGBB0826V
1424401
08512AH
15401HE

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Polyorthocarbonates.
Takekoshi T.
Journal of Polymer Science Part A: Polymer Chemistry, 10(12), 3509-3518 (1972)
Synthesis and mass spectral fragmentations of new spiro heterocycles.
Rahimizadeh M, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 18(6), 689-693 (2007)
The synthesis of sulfur-containing spiro orthocarbonates.
Bromley MK, et al.
Australian Journal of Chemistry, 52(7), 657-662 (1999)
Iodine-Catalyzed Synthesis of Spiroorthocarbonates under Neutral Conditions.
Rahimizadeh M, et al.
ChemInform, 41(1), i-i (2010)
The Reactions of Methyl-and n-Butyllithium with Dichloromethyl Methyl Ether and Dichlorodiphenoxymethane.
McDonald RN and Krueger.
The Journal of Organic Chemistry, 30(12), 4372-4375 (1965)

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