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934844

Sigma-Aldrich

Lithium hexafluorophosphate solution

greener alternative

in ethylene carbonate and ethyl methyl carbonate with vinylene carbonate additive, 1.2 M LiPF6 in EC/EMC=30/70 (w/w) + 1 wt.% VC, battery grade, ≥99.5% trace metals basis

Synonym(s):

1.2 M LiPF6 in EC/EMC=30/70 (w/w) + 1 wt.% VC

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About This Item

UNSPSC Code:
12352600
NACRES:
NA.21

grade

battery grade

Quality Level

Assay

≥99.5% trace metals basis

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

1.2 M (LiPF6)

impurities

≤100.0 ppm H2O
≤250.0 ppm KF

color

clear colorless to faint yellow

density

1.21741 g/mL

application(s)

battery manufacturing

greener alternative category

General description

Our 1.2 M LiPF6 in EC/EMC=30/70 (w/w) + 1 wt.% VC, battery-grade electrolyte solution is designed specifically for use in lithium-ion batteries. This electrolyte contains a high concentration of lithium hexafluorophosphate in a carefully formulated mixture of ethylene carbonate and ethyl methyl carbonate with a vinylene carbonate additive, ensuring excellent battery performance. Our electrolyte solution is of battery-grade quality, with minimized impurities of water, acid, and metals. It is packaged in an aluminum bottle under inert, dry conditions
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Application

We designed our 1.2 M LiPF6 in EC/EMC=30/70 (w/w) + 1 wt.% VC battery-grade electrolyte solution to offer top-notch safety, thermal stability, and exceptional performance for use in lithium-ion batteries. Our careful formulation of ethylene carbonate (EC), ethyl methyl carbonate (EMC), and vinylene carbonate (VC) provides superior electrochemical stability and low viscosity. Additionally, the VC additive contributes to the formation of a solid-electrolyte interface (SEI) during operation, which enhances performance at high operating temperatures, including rate capability and cycling performance.,Our electrolyte exhibits compatibility with a broad range of cathode and anode materials, such as graphite, lithium metal, silicon, LFP, and NMCs, giving versatile battery design options for numerous applications.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT RE 2 Oral

Target Organs

Bone,Teeth, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

71.6 °F

Flash Point(C)

22 °C


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Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation
Alison L, et al.
Chemistry of Materials, 28, 8149?8159-8149?8159 (2016)
Analysis of Vinylene Carbonate (VC) as Additive in Graphite/LiNi0.5Mn1.5O4 Cells
Pritz D, et al.
Journal of the Electrochemical Society, 164, A2625-A2635 (2017)
Effect of Vinylethylene Carbonate and Fluoroethylene Carbonate Electrolyte Additives on the Performance of Lithia-Based Cathodes
Lee S Y, et al.
ACS Omega, 5, 3579-3587 (2020)

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