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270032

Sigma-Aldrich

N,N′-Dimethylethylenediamine

85%

Synonym(s):

1,2-Bis(methylamino)ethane

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About This Item

Linear Formula:
CH3NHCH2CH2NHCH3
CAS Number:
110-70-3
Molecular Weight:
88.15
Beilstein:
878142
EC Number:
203-793-3
MDL number:
MFCD00008290
UNSPSC Code:
12352100
PubChem Substance ID:
24856188
NACRES:
NA.22

Assay

85%

form

liquid

refractive index

n20/D 1.431 (lit.)

bp

119 °C (lit.)

density

0.819 g/mL at 20 °C (lit.)

SMILES string

CNCCNC

InChI

1S/C4H12N2/c1-5-3-4-6-2/h5-6H,3-4H2,1-2H3

InChI key

KVKFRMCSXWQSNT-UHFFFAOYSA-N

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Application

N,N′-Dimethylethylenediamine was used to enhance CO2 adsorption. It was incorporated into H3[(Cu4Cl)3(BTTri)8 (CuBTTri; H3BTTri = 1,3,5-tri(1H-1,2,3-triazol-4-yl)benzene), a water-stable, triazolate-bridged framework, to form a metal–organic framework for CO2 separation.

Other Notes

remainder N-Methylethylenediamine

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

78.8 °F - closed cup

Flash Point(C)

26 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Enhanced carbon dioxide capture upon incorporation of N, N?-dimethylethylenediamine in the metal?organic framework CuBTTri.
McDonald TM, et al.
Chemical Science, 2(10), 2022-2028 (2011)
Kim A Lennox et al.
Oligonucleotides, 16(1), 26-42 (2006-04-06)
A wide variety of modified oligonucleotides have been tested as antisense agents. Each chemical modification produces a distinct profile of potency, toxicity, and specificity. Novel cationic phosphoramidate-modified antisense oligonucleotides have been developed recently that have unique and interesting properties. We
J T Hwang et al.
Nucleic acids research, 27(19), 3805-3810 (1999-09-11)
The formal C1'-oxidation product, 2-deoxyribonolactone, is formed as a result of DNA damage induced via a variety of agents, including gamma-radiolysis and the enediyne antitumor antibiotics. This alkaline labile lesion may also be an intermediate during DNA damage induced by
R Biyik et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 68(2), 394-398 (2007-02-13)
Cu(2+) doped single crystals of [Zn(sac)2(dmen)] (sac: saccharinate, dmen: N,N'-dimethylethylendiamine) and [Zn(sac)2(paen)], (paen: N,N'-bis(3-propylamine)ethylendiamine) complexes have been investigated by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra indicate that Cu(2+) ion substitute with Zn(2+) ion and forms
Ghotas Evindar et al.
The Journal of organic chemistry, 71(5), 1802-1808 (2006-02-25)
A general method for the formation of benzoxazoles via a copper-catalyzed cyclization of ortho-haloanilides is reported. This approach complements the more commonly used strategies for benzoxazole formation which require 2-aminophenols as substrates. The reaction involves an intramolecular C-O cross-coupling of
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