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Key Documents

791776

Sigma-Aldrich

Potassium carbonate

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99%

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About This Item

Formule linéaire :
K2CO3
Numéro CAS:
Poids moléculaire :
138.21
Numéro Beilstein :
4267587
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.21

Qualité

ACS reagent
anhydrous
free-flowing

Niveau de qualité

Gamme de produits

Redi-Dri

Pureté

≥99%

Forme

powder

Impuretés

≤0.005% silica
≤0.01% insolubles

pH

11-13 (25 °C, 138 g/L)

Pf

891 °C (lit.)

Traces d'anions

chloride (Cl-): ≤0.003%
phosphate (PO43-): ≤0.001%
sulfur compounds (as SO42-): ≤0.004%

Traces de cations

Ca: ≤0.005%
Fe: ≤5 ppm
Mg: ≤0.002%
Na: ≤0.02%
heavy metals (as Pb): ≤5 ppm

Chaîne SMILES 

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

Clé InChI

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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Description générale

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

Application

Potassium carbonate has been used in the preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.

It may be used:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.
  • As a base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • In the Heck reaction of styrene and bromobenzene.

Caractéristiques et avantages

  • Increased efficiency – Eliminate time and effort of loosening hardened powders
  • Safety – Avoid risks of using tools of force to break up clumps
  • Economy – Faster preparation and solvation increase productivity and reduce costs
  • Assured quality – Excellent, expert-tested quality with no anti-caking agents
  • Flexible volumes – Available from research amounts to scale-up quantities

Informations légales

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictogrammes

Exclamation mark

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Adam F Nugraha et al.
Polymers, 12(7) (2020-07-24)
Several methods to synthesize poly(phenylene) block copolymers through the nickel coupling reaction were attempted to reduce the use of expensive nickel catalysts in polymerization. The model reaction for poly(phenylene) having different types of dichlorobenzene derivative monomers illustrated the potential use
Yusuke Yagi et al.
Organic & biomolecular chemistry, 13(4), 1113-1121 (2014-11-26)
Fluorine-18 labeled radiotracers, such as [(18)F]fluorodeoxyglucose, can be used as practical diagnostic agents in positron emission tomography (PET). Furthermore, the properties of pharmaceuticals can be enhanced significantly by the introduction of fluorine groups into their original structures, and significant progress
Ellen Dirkx et al.
Journal of molecular and cellular cardiology, 76, 208-217 (2014-09-01)
In the insulin resistant heart, energy fuel selection shifts away from glucose utilization towards almost complete dependence on long-chain fatty acids (LCFA). This shift results in excessive cardiac lipid accumulation and eventually heart failure. Lipid-induced cardiomyopathy may be averted by
Brian Capozzi et al.
Journal of the American Chemical Society, 136(29), 10486-10492 (2014-07-09)
We have measured the single-molecule conductance of a family of oligothiophenes comprising 1-6 thiophene moieties terminated with methyl-sulfide linkers using the scanning tunneling microscope-based break-junction technique. We find an anomalous behavior: the peak of the conductance histogram distribution does not
K M Frankowski et al.
Journal of dairy science, 97(9), 5356-5370 (2014-07-16)
Many food companies are trying to limit the amount of sodium in their products. Permeate, the liquid remaining after whey or milk is ultrafiltered, has been suggested as a salt substitute. The objective of this study was to determine the

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