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Sigma-Aldrich

Tin(II) iodide

AnhydroBeads, −10 mesh, 99.99% trace metals basis

Synonyme(s) :

Stannous iodide, Tin diiodide

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About This Item

Formule linéaire :
SnI2
Numéro CAS:
Poids moléculaire :
372.52
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Gamme de produits

AnhydroBeads

Niveau de qualité

Pureté

99.99% trace metals basis

Forme

beads

Impuretés

≤150.0 ppm Trace Metal Analysis

Taille des particules

−10 mesh

Point d'ébullition

714 °C (lit.)

Pf

320 °C (lit.)

Densité

5.28 g/mL at 25 °C (lit.)

Chaîne SMILES 

I[SnH2]I

InChI

1S/2HI.Sn/h2*1H;/q;;+2/p-2

Clé InChI

JTDNNCYXCFHBGG-UHFFFAOYSA-L

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Description générale

Tin(II) iodide AnhydroBeads−10 mesh, 99.99% trace metals basis comes as beads with red to purple in color with applications in semiconductor research, solar cells, material science, chemical synthesis, catalysis, and photonics. Tin (II) iodide is widely used as a precursor toprepare lead-free non-toxic hybrid perovskite materials. Tin-based perovskitesshow excellent electrical and optical properties such as high charge carrier mobility,absorption coefficient, and small exciton binding energies.

Application

Tin(II) iodide (SnI₂) is a versatile compound with a range of applications in research, particularly in semiconductor technology, solar cells, chemical synthesis, catalysis etc. SnI₂ is used in perovskite solar cells as a precursor for tin-based perovskites or as an additiveto improve device stability and performance. The addition of a small amount of 2D tin film induces well-defined orientation and superior crystallinity in formamidinium tin iodide (FASnI3) films. This results in the longer life of charge carriers and improves the performance of hybrid perovskite solar cell (HPSC). [Ref] It can also be used to preparesolution-processable lamellar hybrid [CH3(CH2)11NH3]SnI3semiconductor.Its catalytic properties can be leveraged to develop new synthetic methodologies such as reductions, cyclizations, and coupling reactions. It is suitable to be used in photonic applications, including sensors and photovoltaic devices. It is used as a deposition material for preparing thin films for use in electronic and optoelectronic devices. Techniques like chemical vapor deposition (CVD) and physical vapor deposition (PVD) are explored for creating high-quality films. In a study, it is found that when a novel catalytic system comprised of tin sulfide (SnS) nanoflakes as a solid catalyst and tin iodide (SnI2) as a dual-functional electrolyte additive, the Li-air battery enables operating at high current rates up to 10 000 mA g−1 (corresponding to 1 mA cm−2). Also it has been observed that that the role of the SnI2 is not only reacting with the lithium anode to provide protection but reducing the charge potential by promoting catalytic decomposition of the Li2O2.

Caractéristiques et avantages

Tin(II) iodide AnhydroBeads, −10 mesh, 99.99% trace metals basis is designed and tested under stringent dry manufacturing conditions to ensure low water content, trace metal purity of 99.99%, and low surface area-to-volume ratio. The salt possesses excellent electrical and optical properties such as high charge carrier mobility,absorption coefficient, and small exciton binding energies. The advantages of our AnhydroBeads salts are as follows:

1) Reduced uptake rate of environmental moisture minimizes caking, dusting, and static buildup for repeated easy handling.

2) Higher crucible packing densities and lower volatility in high-temperature solid state procedures.

3) Easier pneumatic loading of salts to sample chambers due to less clogging issues associated with powdered salt counterparts.

Informations légales

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

À utiliser avec

Pictogrammes

Health hazardCorrosionExclamation mark

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 3

Organes cibles

Cardio-vascular system,hematopoietic system, Respiratory system

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Perovskite multifunctional logic gates via bipolar photoresponse of single photodetector
Kim W, et al.
Nature Communications, 13, 720-720 (2022)
Novel Co-Catalytic Activities of Solid and Liquid Phase Catalysts in High-Rate Li-Air Batteries
Zhang C, et al.
Advanced Energy Materials, 12, 2201616-2201616 (2022)
Liang, K. et al.
Chemistry of Materials, 10, 403-403 (1998)
A Cation-Exchange Approach for the Fabrication of Efficient Methylammonium Tin Iodide Perovskite Solar Cells
Angewandte Chemie (International ed. in English), 58, 6688-6692 (2019)
Kohei Nishimura et al.
ACS applied materials & interfaces, 11(34), 31105-31110 (2019-08-07)
In the composition of Q0.1(FA0.75MA0.25)0.9SnI3, Q is replaced with Na+, K+, Cs+, ethylammonium+ (EA+), and butylammonium+ (BA+), respectively, and the relationship between actually measured lattice strain and photovoltaic performances is discussed. The lattice strain evaluated by the Williamson-hall plot of

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