208795

S-Methyl methanethiosulfonate

97%

• Synonyme(s) : S-Methyl thiomethanesulfonate, MMTS
• Formule linéaire : CH₃SO₂SCH₃
• Numéro CAS: 2949-92-0
• Poids moléculaire : 126.20
• Beilstein: 1446059
• Numéro CE : 220-970-0
• Numéro MDL: MFCD00007565
• Code UNSPSC : 12352100
• ID de substance PubChem : 24852530
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 200
• Essai: 97%
• Forme: liquid
• Indice de réfraction: n20/D 1.513 (lit.)
• pb: 69-71 °C/0.4 mmHg (lit.)
• Solubilité: DMF: soluble 1:1; chloroform: soluble 200 ul per mL, clear, faintly yellow-green; water: soluble 1:5
• Densité: 1.337 g/mL at 25 °C (lit.)
• Groupe fonctionnel: disulfide
• Chaîne SMILES: CSS(C)(=O)=O
• InChI: 1S/C2H6O2S2/c1-5-6(2,3)4/h1-2H3
• Clé InChI: XYONNSVDNIRXKZ-UHFFFAOYSA-N

Description

Description générale

S-Methyl methanethiosulfonate is a reagent used to synthesize thiols and thioesters. Used as cross-linking agent to prepare polymer networks. Interaction of S-methyl methanethiosulfonate (MMTS) with dipalmitoylphosphatidylcholine (DPPC) bilayers has been investigated by FTIR and surface-enhanced Raman spectroscopy.

Application

S-Methyl methanethiosulfonate was used as sulfenylating agent for β-keto sulfoxides, methylene compounds, half-esters of malonic acids and aryl Grignard reagents. It was also used as a reagent to trap the natural thiol-disulfide state of the proteins.

Informations sur la sécurité

• Code de la classe de stockage: 10 - Combustible liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 188.6 °F - closed cup
• Point d'éclair (°C): 87 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Gloves, type ABEK (EN14387) respirator filter