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8.04604

Hydrazin hydrate solution

80% solution in water, for synthesis

Synonym(s):

Hydrazine hydrate

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About This Item

UNSPSC Code:
12352402
NACRES:
NA.22
Form:
solution
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Product Name

Hydrazin hydrate (80% solution in water), for synthesis

vapor pressure

13 hPa ( 20 °C)

Quality Level

form

solution

autoignition temp.

310 °C

expl. lim.

4.7-99 % (v/v) refers to pure substance()

reaction suitability

reagent type: reductant

pH

10.6-10.7 (20 °C, 10 g/L in H2O)

bp

117-119 °C/1013 hPa

mp

-60 °C

density

1.02 g/cm3 at 20 °C

storage temp.

15-25°C

Application

Hydrazin hydrate (80% solution in water) can be used as a reducing agent for the reduction of exfoliated graphene oxide (GO), which is used for the preparation of GO nanocomposites. It is also used as a reagent in the synthesis of 3-amino-2-thiohydantoins by reacting with alkyl isothiocynatocarboxylates.

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This Item
8.04608751855433632
Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

reaction suitability

reagent type: reductant

reaction suitability

-

reaction suitability

-

reaction suitability

-

density

1.02 g/cm3 at 20 °C

density

1.03 g/cm3 at 20 °C

density

0.779 g/mL at 25 °C

density

0.886 g/mL at 25 °C

mp

-60 °C

mp

-51.7 °C

mp

-

mp

-

storage temp.

15-25°C

storage temp.

15-25°C

storage temp.

-

storage temp.

-

form

solution

form

liquid

form

liquid

form

liquid


signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

wgk

WGK 3

flash_point_f

195.8 °F - closed cup - DIN 51758

flash_point_c

91 °C - closed cup - DIN 51758

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

7803-57-8

CAS No.

7803-57-8

CAS No.


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthetical Application of Alkyl 2-isothiocyanatocarboxylates. A Simple Synthesis of 5-Substituted-3-amino-2-thioxo-4-imidazolidinones (3-Amino-2-thiohydantoins)
Floch L, et al.
Molecules (Basel), 4(10), 279-286 (1999)
Hydroxypropyl-β-cyclodextrin-polyurethane/graphene oxide magnetic nanoconjugates as effective adsorbent for chromium and lead ions
Nasiri, Shohreh and Alizadeh, Nina
Carbohydrate Polymers, 259, 117731-117731 (2021)



Global Trade Item Number

SKUGTIN
804604025004022536385600
804604901004022536546452
804604905504022536385624
804604100004022536385617

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. It is 80% of hydrazine hydroxide in water (about 52% of hydrazine in water) or 80% of hydrazine in water. There is no MW on page. I thought that is less than 1 molecule of water to 1 molecule of hydrazine (sth like hydrazine half-hydrate).

    1 answer
    1. It is the former. Product 8.04604 is approximately 80 percent hydrazine hydrate by weight, which corresponds to 51.2 percent hydrazine by weight. Based on a density of 1.02 g/mL for this solution, which is 51.2 percent hydrazine, and a molecular weight of 32.05 for hydrazine (N2H4), the molarity of this solution is approximately 16 M.

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