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Merck

934046

Sigma-Aldrich

Ethyl 1,1,2,2-tetrafluoroethyl ether

greener alternative

≥99%, anhydrous, battery grade

Synonym(e):

1,1,2,2-Tetrafluoroethyl ethyl ether, 1-Ethoxy-1,1,2,2-tetrafluoroethane, ETFE, HFE 374

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About This Item

Empirische Formel (Hill-System):
C4H6F4O
CAS-Nummer:
Molekulargewicht:
146.08
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.21

Qualität

battery grade

Qualitätsniveau

Assay

≥99%

Form

liquid

Grünere Alternativprodukt-Eigenschaften

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sustainability

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Verunreinigungen

≤100 ppm HF
≤200 ppm H2O

bp

58 °C

mp (Schmelzpunkt)

-86 °C (lit.)

Dichte

1.21 g/mL

Anwendung(en)

battery manufacturing

Grünere Alternativprodukt-Kategorie

SMILES String

FC(F)(OCC)C(F)F

InChI

1S/C4H6F4O/c1-2-9-4(7,8)3(5)6/h3H,2H2,1H3

InChIKey

HBRLMDFVVMYNFH-UHFFFAOYSA-N

Allgemeine Beschreibung

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a fluorinated linear ether that has several key properties that make it useful in batteries. First, ETFE is miscible with many polar organic solvents used in electrolyte formulations, which improves the ionic conductivity of the battery. Additionally, ETFE has a relatively low viscosity (486 mPa•s at 23 °C) and a low boiling point (58 °C), which make it a versatile diluent for low-temperature applications. Our battery grade ETFE is manufactured with high purity and low trace impurities of water and acid.
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Anwendung

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a highly effective additive in lithium-ion batteries and sodium-ion batteries for improving battery performance, increasing safety, and reducing flammability. ETFE is a versatile co-solvent with high miscibility, which allows it to be blended with other solvents to achieve high ionic conductivities. It is also a good SEI-forming electrolyte additive, stabilizing the Na electrode surface and enhancing the stability of high-voltage batteries. ETFE is particularly useful as an electrolyte co-solvent in lithium-sulfur (Li-S) batteries. Studies have shown that ETFE-containing electrolytes improve the stability of the electrolyte/anode interface and enhance the cycling, rate, and self-discharging of the Li-S cell more than glyme-based cosolvents or unblended solvents. With its unique properties and proven effectiveness, battery-grade ETFE is an excellent choice for manufacturers looking to create high-performing, reliable, and safe lithium-ion and sodium-ion batteries.

Piktogramme

Flame

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Flam. Liq. 2

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

5.0 °F

Flammpunkt (°C)

-15 °C


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Die Dokumentenbibliothek aufrufen

Lithium/sulfur batteries with mixed liquid electrolytes based on ethyl 1,1,2,2-tetrafluoroethyl ether,
Hai, et al.
Electrochimica Acta, 161, 55-62 (2015)
Synthesis and electrochemical properties of partially fluorinated ether solvents for lithium sulfur battery electrolytes,
Yue , et al.
Journal of Power Sources, 401, 271-277 (2018)
Nasim Azimi et al.
ACS applied materials & interfaces, 7(17), 9169-9177 (2015-04-14)
A high performance Li-S battery with novel fluoroether-based electrolyte was reported. The fluorinated electrolyte prevents the polysulfide shuttling effect and improves the Coulombic efficiency and capacity retention of the Li-S battery. Reversible redox reaction of the sulfur electrode in the

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