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Merck

449903

Sigma-Aldrich

Lithiumfluorid

greener alternative

≥99.99% trace metals basis

Synonym(e):

Fluorolithium

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About This Item

Lineare Formel:
LiF
CAS-Nummer:
Molekulargewicht:
25.94
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

Qualität

anhydrous

Qualitätsniveau

Assay

≥99.99% trace metals basis

Form

powder and chunks

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
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sustainability

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Verunreinigungen

≤100.0 ppm Trace Metal Analysis

bp

1673 °C/1 atm (lit.)

mp (Schmelzpunkt)

845 °C (lit.)

Löslichkeit

aqueous acid: slightly soluble(lit.)

Dichte

2.64 g/mL at 25 °C (lit.)

Grünere Alternativprodukt-Kategorie

SMILES String

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChIKey

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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Allgemeine Beschreibung

Lithium fluoride is a white crystalline solid with a high melting point. It is widely applied in the field of rechargeable batteries, storage devices, and thermoluminescent materials. LiF is also used as a coupling layer in OLED or PLED devices to enhance electron injection. On the other hand, it is preferred for optical applications due to its wide band gap, which allows it to transmit light efficiently.
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Anwendung

Lithium fluoride can be used:
  • As an additive to fabricate SiO@C/graphite composite anode materials for Li-ion batteries. LiF stabilizes solid electrolyte interphase (SEI) and enhances initial coulombic efficiency.
  • As a critical component in SEI for stabilizing the SEI layer and improving the cycling efficiency of Li metal batteries.
  • To fabricate electron contacts for high-efficiency n-type crystalline silicon solar cells.
  • To prepare solid-state light sources for radiation imaging detectors.
  • To synthesize highly crystalline MXene for asymmetric supercapacitor applications. And also, lightweight, flexible, and hydrophobic MXene foam with reasonable strength, high electrical conductivity, and an outstanding EMI-shielding performance.
  • As an electron-injection layer to fabricate ITO/PEDOT:PSS/perovskite/B3PYMPM/ LiF/Al OLED device with a quantum efficiency of 20%.

Piktogramme

Skull and crossbones

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Die Dokumentenbibliothek aufrufen

Improving the electrochemical properties of a SiO@C/graphite composite anode for high-energy lithium-ion batteries by adding lithium fluoride
Mao Xia, et al.
Applied Surface Science, 480, 410-418 (2019)
A safe etching route to synthesize highly crystalline Nb2CTx MXene for high performance asymmetric supercapacitor applications
Junpeng Xiao, et al.
Electrochimica Acta, 337, 135803-135803 (2020)
Radiat. Prot. Dosim., 66, 101-101 (1996)
Photoluminescence of colour centres in lithium fluoride thin films: from solid-state miniaturised light sources to novel radiation imaging detectors
R M Montereali, et al.
Journal of Luminescence, 170, 761-769 (2016)
Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent
Kebin Lin, et al.
Nature, 562, 245-248 (2018)

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