365270

α-Bromphenylessigsäure-methylester

97%

• Lineare Formel: C₆H₅CH(Br)CO₂CH₃
• CAS-Nummer: 3042-81-7
• Molekulargewicht: 229.07
• MDL-Nummer: MFCD00013535
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24862500
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 97%
• Form: liquid
• Brechungsindex: n20/D 1.553 (lit.)
• bp: 113 °C/3 mmHg (lit.)
• Dichte: 1.455 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: bromo; ester; phenyl
• Lagertemp.: 2-8°C
• SMILES String: COC(=O)C(Br)c1ccccc1
• InChI: 1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
• InChIKey: NHFBYYMNJUMVOT-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

Anwendung

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 235.4 °F - closed cup
• Flammpunkt (°C): 113 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter