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203521

Sigma-Aldrich

Lanthan(III)-chlorid Heptahydrat

99.999% trace metals basis

Synonym(e):

Lanthanum trichloride heptahydrate, Lanthanum(3+) trichloride heptahydrate

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About This Item

Lineare Formel:
LaCl3 · 7H2O
CAS-Nummer:
Molekulargewicht:
371.37
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

Qualitätsniveau

Assay

99.999% trace metals basis

Form

solid

Eignung der Reaktion

reagent type: catalyst
core: lanthanum

Verunreinigungen

≤15.0 ppm Trace Rare Earth Analysis

mp (Schmelzpunkt)

91 °C (dec.) (lit.)

SMILES String

O.O.O.O.O.O.O.Cl[La](Cl)Cl

InChI

1S/3ClH.La.7H2O/h3*1H;;7*1H2/q;;;+3;;;;;;;/p-3

InChIKey

FDFPDGIMPRFRJP-UHFFFAOYSA-K

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Allgemeine Beschreibung

Lanthanum(III)chloride heptahydrate is a mild, inexpensive, and moisture-stable heterogeneouscatalyst widely used in several organic transformations.

Anwendung

Lanthanum(III) chloride heptahydrate can be used as an efficient catalyst for :
  • Solvent-free preparation of substituted alkenes via Knoevenagel condensation.
  • One-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones.
It can be used as a precursor to synthesize La/V co-doped TiO2 nanoparticles through the sol-gel method. La co-doped TiO2 nanopowder show enhanced photocatalytic activity.

Biochem./physiol. Wirkung

Calciumkanal Blocker

Signalwort

Danger

Gefahreneinstufungen

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

Lagerklassenschlüssel

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flammpunkt (°F)

does not flash

Flammpunkt (°C)

does not flash

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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Journal of inorganic biochemistry, 117, 18-24 (2012-10-20)
Lanthanum chloride (LaCl(3)) is a good inhibitor of both the cytosolic and mitochondrial thioredoxin reductase with IC(50) values of 1.75 and 7.46 μM, respectively. On the contrary, the related enzyme glutathione reductase is not inhibited by lanthanum ions even at
Adan Schafer Medina et al.
Journal of radioanalytical and nuclear chemistry, 324(3), 1021-1030 (2020-07-01)
Microliter volumes are used in electrochemical detection and preconcentration of radionuclides to reduce the dose received by researchers and equipment. Unfortunately, there is a lack of analysis of radionuclides with coupled electrochemical techniques and microliter volume reactors. The goals of
T Wu et al.
American journal of physiology. Heart and circulatory physiology, 301(1), H69-H78 (2011-04-05)
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Tawnya G Flick et al.
Journal of the American Society for Mass Spectrometry, 23(11), 1885-1895 (2012-09-06)
Addition of 1.0 mM LaCl(3) to aqueous ammonium acetate solutions containing proteins in their folded native forms can result in a significant increase in the molecular ion charging obtained with electrospray ionization as a result of cation adduction. In combination

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