176494

Europium-tris[3-(trifluormethylhydroxymethylen)-(+)-campherat]

• Synonym(e): Eu(facam)₃, Eu(tfc)₃, Tris-[3-(trifluoracetyl)-d-camphorato]-europium(III), Tris-[3-(trifluormethyl-hydroxymethylen)-d-camphorato]-europium(III)
• Empirische Formel (Hill-System): C₃₆H₄₂EuF₉O₆
• CAS-Nummer: 34830-11-0
• Molekulargewicht: 893.66
• EG-Nummer: 252-232-9
• MDL-Nummer: MFCD00074803
• UNSPSC-Code: 12352115
• PubChem Substanz-ID: 24850581
• NACRES: NA.22

Eigenschaften

• Optische Aktivität: [α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
• Methode(n): NMR: suitable
• Funktionelle Gruppe: fluoro; ketone
• SMILES String: CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F
• InChI: 1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;
• InChIKey: BWIHMSGCCRUUCZ-NCJHBDPTSA-K

Beschreibung

Anwendung

Reactant involved in:

• The synthesis of europium acetylcamphorate phosphine oxide complexes
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)