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2-Cyclohepten-1-on
80%, technical grade
Synonym(e):
2-Cycloheptenone, Tropilene
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About This Item
Empfohlene Produkte
Qualität
technical grade
Qualitätsniveau
Assay
80%
Form
liquid
Brechungsindex
n20/D 1.494 (lit.)
Dichte
0.988 g/mL at 25 °C (lit.)
Funktionelle Gruppe
ketone
Lagertemp.
2-8°C
SMILES String
O=C1CCCCC=C1
InChI
1S/C7H10O/c8-7-5-3-1-2-4-6-7/h3,5H,1-2,4,6H2
InChIKey
WZCRDVTWUYLPTR-UHFFFAOYSA-N
Allgemeine Beschreibung
2-Cyclohepten-1-one is an α,β-enone and its regioselective reaction with allyl indium reagent in the presence of TMSCl has been reported. It reacts with Bu2Zn in the presence of catalytic amounts of Cu(OTf)2 and CH2-bridged azolium salts to give (S)-3-butylcycloheptanone.
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Acute Tox. 4 Oral
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 1
Flammpunkt (°F)
154.4 °F - closed cup
Flammpunkt (°C)
68 °C - closed cup
Persönliche Schutzausrüstung
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Neurobiology of aging, 12(3), 227-231 (1991-05-01)
A severe age-dependent depletion of reduced glutathione (GSH) occurs in rat forebrain at 1-3 h from intraperitoneal injection of the electrophilic agents cyclohexene-1-one and cycloheptene-1-one. Chronic pretreatment with central dopamine agonists (i.e., ergot alkaloids; particularly, dihydroergocriptine) partially counteracts the GSH
The Journal of organic chemistry, 77(8), 4079-4086 (2012-03-30)
A series of hydroxy-amide functionalized azolium salts have been designed and synthesized for Cu-catalyzed asymmetric conjugate addition reaction. The (CH(2))(2)-bridged hydroxy-amide functionalized azolium ligand precursors 2, in addition to the previously reported CH(2)-bridged azolium salts 1, have been prepared from
Journal of pharmaceutical sciences, 69(5), 527-531 (1980-05-01)
A stirred transfer cell containing equal volumes of light liquid paraffin and an aqueous phase at 37 degrees was used to demonstrate the feasibility of calculating the partition coefficient of an unstable compound by kinetic analysis. Cyclohept-2-enone was chosen since
Life sciences, 44(6), 417-424 (1989-01-01)
To search for a technique to deplete reduced glutathione (GSH) in brain, the influence of various types of compounds on brain GSH levels was investigated in mice. Of the compounds tested, cyclohexene-1-one, cycloheptene-1-one and diethyl maleate were shown to be
Studies on the reactions of α, β-enones with allyl indium reagent; effects of TMSCl as promoter on regioselectivity.
Tetrahedron Letters, 42(1), 37-39 (2001)
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