140732

N,N-Dimethylformamiddimethylacetal

technical grade, 94%

• Synonym(e): 1,1-Dimethoxy-N,N-dimethylmethylamin, 1,1-Dimethoxytrimethylamin
• Lineare Formel: (CH₃)₂NCH(OCH₃)₂
• CAS-Nummer: 4637-24-5
• Molekulargewicht: 119.16
• Beilstein: 506020
• EG-Nummer: 225-063-3
• MDL-Nummer: MFCD00008482
• UNSPSC-Code: 12352302
• PubChem Substanz-ID: 24848474
• NACRES: NA.22

Eigenschaften

• Qualität: technical grade
• Qualitätsniveau: 200
• Assay: 94%
• Form: liquid
• Eignung der Reaktion: reaction type: C-C Bond Formation
• Brechungsindex: n20/D 1.396 (lit.)
• bp: 102-103 °C/720 mmHg (lit.)
• Dichte: 0.897 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: amine; ether
• SMILES String: COC(OC)N(C)C
• InChI: 1S/C5H13NO2/c1-6(2)5(7-3)8-4/h5H,1-4H3
• InChIKey: ZSXGLVDWWRXATF-UHFFFAOYSA-N

Beschreibung

Anwendung

N,N-Dimethylformamide dimethyl acetal (DMF-DMA) can be used as: 

• An organocatalyst for the synthesis of 1,2-disubstituted-3,4-dihydronaphthalenes by the reaction of vinylarenes and electron-deficient alkynes.       
• A building block for the preparation of heterocyclic compounds such as enamines and amidines via formylation of methylene and amino groups.       
• A reagent in the synthesis of 1,4-diaryl-piperazine-2,5-diones by reacting with chloroacetamides.        
• A reagent along with enamine and alkyne for the preparation of 2,3,4,5-tetrasubstituted pyridine derivatives by three-component coupling reaction in the presence of Me₃SiCl.

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H317,H318,H332
• P-Sätze: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Sens. 1
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): 42.8 °F
• Flammpunkt (°C): 6 °C
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter