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137286

Sigma-Aldrich

5-Bromsalicylaldehyd

98%

Synonym(e):

5-Brom-2-hydroxy-benzaldehyd

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About This Item

Lineare Formel:
BrC6H3-2-(OH)CHO
CAS-Nummer:
1761-61-1
Molekulargewicht:
201.02
Beilstein:
774710
EG-Nummer:
217-167-2
MDL-Nummer:
MFCD00003330
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24848318
NACRES:
NA.22

Qualitätsniveau

200

Assay

98%

Form

powder

mp (Schmelzpunkt)

102-106 °C (lit.)

Funktionelle Gruppe

aldehyde
bromo

SMILES String

Oc1ccc(Br)cc1C=O

InChI

1S/C7H5BrO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H

InChIKey

MKKSTJKBKNCMRV-UHFFFAOYSA-N

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Allgemeine Beschreibung

5-Bromosalicylaldehyde reacts with 1,2-bis(4-chloro-2-aminophenoxy)ethane to yield Schiff base ligand 1,2-bis(2-(5-bromo-2-hydroxybenzilidenamino)-4-chlorophenoxy)ethane. It is the starting reagent for the synthesis of diarylamino-substituted N-methyl tetrahydrosalen ligand.

5-Bromosalicylaldehyde is generally used to synthesize schiff bases, and triphenyltin complexes.

Anwendung

5-Bromosalicylaldehyde was used for chemical derivatization during amine quantiifcation in poly (ethylene terephthalate) (PET) film and PET scaffold.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

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Analysenzertifikate (COA)

Lot/Batch Number
0000226928
STBL2622
0000226928
0000231505
0000231504

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Salih Ilhan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 632-642 (2013-10-08)
A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal salts and the novel Schiff base. The molar conductivity properties of the complexes were studied
L N Corîci et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 16(6), 946-953 (2017-04-27)
The network of chemical reactions of 2,6-bis(5-bromo-2-hydroxybenzylidene)cyclohexanone (BHBC) when subjected to light and different pH values has been investigated. The pH dependent species involved in the chemical network have been identified and characterized by NMR and UV-VIS spectroscopy. Direct pH
Masahito Yoshida et al.
Chemical & pharmaceutical bulletin, 68(3), 220-226 (2019-10-05)
This study demonstrates the structure-activity relationship of Col-003, a potent collagen-heat-shock protein 47 (Hsp47) interaction inhibitor. Col-003 analogues were successfully synthesized by Pd(0)-catalyzed cross-coupling reactions of 5-bromosalicylaldehyde derivatives with alkyl-metal species, and the inhibitory activities of the synthetic analogues were
Mauricio Quiroz-Guzman et al.
Dalton transactions (Cambridge, England : 2003), 40(43), 11458-11468 (2011-09-22)
A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Hartwig-Buchwald amination of the tert-butyldimethylsilyl-protected 5-bromo-N-methylsalan ligand. Reaction of (An2N)LH(2) or its bromo analogue with Ti(O(i)Pr)(4)
Synthesis, characterization, and cytotoxic activity of triphenyltin complexes of N-(5-bromosalicylidene)-?-amino acids
Yao Y, et al.
Main Group Metal Chemistry, 40, 93-99 (2017)
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