M8703
Silver methanesulfonate
98%
Synonym(s):
Methanesulfonic acid silver salt
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About This Item
Linear Formula:
AgSO3CH3
CAS Number:
Molecular Weight:
202.97
MDL number:
PubChem Substance ID:
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Assay
98%
mp
252-256 °C (lit.)
SMILES string
[Ag+].CS([O-])(=O)=O
InChI
1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
InChI key
MLKQJVFHEUORBO-UHFFFAOYSA-M
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Application
Catalyst for:
- Heterocyclization reactions
- CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,ß-unsaturated ketones and esters
Precursor to alkyl methanesulfonate derivatives useful as alkylating agents for aromatic compounds.
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Tetrahedron Letters, 22, 537-537 (1981)
Tsung-Ming Shih et al.
Chemico-biological interactions, 187(1-3), 207-214 (2010-03-13)
This study compared the ability of nine oximes (HI-6, HLö7, MMB-4, TMB-4, carboxime, ICD585, ICD692, ICD3805, and 2-PAM) to reactivate in vivo cholinesterase (ChE) in blood, brain, and peripheral tissues in guinea pigs intoxicated by one of four organophosphorus nerve
Statistically sound calibration curves for chromatographic methods involving negative response data.
L E Vanatta et al.
Journal of chromatographic science, 49(8), 610-611 (2011-08-24)
A statistical procedure is presented for calibrating chromatographic methods that generate negative chromatographic peaks. The technique is illustrated via data collected during the ion-chromatographic analysis of the ammonium ion in methansulfonic-acid solutions. A peak-integration protocol is explained and subsequent regression
Neal W Sach et al.
Organic letters, 14(15), 3886-3889 (2012-07-18)
A general synthesis of aryl ethers from primary and secondary alcohols and aryl mesylates is presented. The reaction proceeds via a sulfonyl-transfer mechanism. In this paper, we compare the sulfonyl transfer reaction to Mitsunobu ether formation. The reaction can be
Xiangke Chen et al.
The journal of physical chemistry. B, 114(47), 15546-15553 (2010-11-11)
The molecular organization at the aqueous dimethyl sulfoxide (DMSO) and methanesulfonic acid (MSA) surfaces was investigated using vibrational sum frequency generation (VSFG) spectroscopy and molecular dynamics (MD) simulation. The molecular orientation of surface DMSO and MSA is deduced based on
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