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15594

Sigma-Aldrich

Borane tetrahydrofuran complex solution

purum, ~1 M in THF

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About This Item

Linear Formula:
BH3OC4H8
CAS Number:
14044-65-6
Molecular Weight:
85.94
Beilstein:
3668402
MDL number:
MFCD00012429
UNSPSC Code:
12352000
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grade

purum

reaction suitability

reagent type: reductant

concentration

~1 M in THF

impurities

≤20% diethylether

density

0.87 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

B.C1CCOC1

InChI

1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3

InChI key

RMCYTHFAWCWRFA-UHFFFAOYSA-N

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Application

New, Safer, NIMBA-Stabilized BH3 THF Solutions

Other Notes

Reducing agent[1]; Selective reduction of certain oximes to hydroxylamines[2]; Preparation of chiral boranes as Lewis acid mediators[3][4]

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F.A.J. Kerdesky et al.
Synthetic Communications, 21, 2203-2203 (1991)
E.R. Parmee et al.
Journal of the American Chemical Society, 113, 9365-9365 (1991)
G.A. Molander et al.
Journal of the American Chemical Society, 114, 2759-2759 (1992)
H.C. Brown et al.
Tetrahedron, 35, 567-567 (1979)

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