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D216402

Sigma-Aldrich

2,2′-Dipyridylamine

98%

Synonym(s):

bipyam

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About This Item

Empirical Formula (Hill Notation):
C10H9N3
CAS Number:
1202-34-2
Molecular Weight:
171.20
Beilstein:
127131
EC Number:
214-864-3
MDL number:
MFCD00006247
UNSPSC Code:
12352100
PubChem Substance ID:
24893648
NACRES:
NA.22
form:
solid
Assay:
98%

Quality Level

200

Assay

98%

form

solid

bp

222 °C/50 mmHg (lit.)

mp

90-92 °C (lit.)

SMILES string

N(c1ccccn1)c2ccccn2

InChI

1S/C10H9N3/c1-3-7-11-9(5-1)13-10-6-2-4-8-12-10/h1-8H,(H,11,12,13)

InChI key

HMMPCBAWTWYFLR-UHFFFAOYSA-N

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Application

2,2′-Dipyridylamine (bipyam) can be used:
  • As a bidentate N-donor ligand in the synthesis of various metal complexes.
  • To synthesize Pd-polyoxovanadates, heterogeneous catalyst for the oxidation of benzylic hydrocarbons.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBQ0269V
BCBP7562V
BCBM2313V
BCBL9451V
BCBL7008V

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Venugopal Rajendiran et al.
Dalton transactions (Cambridge, England : 2003), (16)(16), 2157-2170 (2008-04-10)
A series of mixed ligand ruthenium(II) complexes [Ru(Hdpa)2(diimine)](ClO4)2, 1-5 where Hdpa is 2,2'-dipyridylamine and diimine is 1,10-phenanthroline (phen) and a modified/extended 1,10-phenanthroline such as, 5,6-dimethyl-1,10-phenanthroline (5,6-dmp), dipyrido[3,2-d:2',3'-f]quinoxaline (dpq), 5-methyldipyrido[3,2-d:2',3'-f]quinoxaline (mdpq) and dipyrido[3,2-a:2',3'-c]phenazine (dppz) have been isolated and characterized by analytical
Structural diversity of manganese (II) complexes containing 2, 2′-dipyridylamine and benzenedicarboxylates. Conformational analysis of tere-, iso-and phthalate ions: An experimental and quantum chemical approach
Radovanovic L, et al.
Inorgorganica Chimica Acta, 445, 46-56 (2016)
Mohan N Patel et al.
Journal of enzyme inhibition and medicinal chemistry, 26(2), 188-197 (2010-06-30)
The copper(II) complexes of the type [Cu(SPF)(A(n))Cl]/[Cu(PFL)(A(n))Cl] (where SPF is sparfloxacin, PFL is pefloxacin and A(n) is 2,2'-dipyridylamine/pyridine-2-carboxalehyde/thiophene-2-carboxaldehyde) were synthesised and were found to have a pyramidal geometry with a square base. The superoxide dismutase (SOD) like activity of the
Sanela Martić et al.
Inorganic chemistry, 47(18), 8315-8323 (2008-08-20)
The syntheses of new blue luminescent N(2)-modified guanosine derivatives with chromophores p-4,4'-biphenyl-NPh2 (1a), p-4,4'-biphenyl-N(2-py)2 (1b), and p-4,4'-biphenyl-2-(2'-pyridyl)benzimidazolyl (1c), respectively, have been achieved. These new N(2)-guanosines are moderate blue emitters with lambda(max) = 395 nm (1a), 370 nm (1b), and 403
Kyeung Joo Jang et al.
Biophysical chemistry, 148(1-3), 138-143 (2010-03-31)
[M(Hdpa)(2)(NO(3))(n)](x+) (M=Zn(II), Cd(II), Cu(II) and Ni(II), n=1,2, and x=0, 1) complexes were synthesized, and their activity as catalysts for DNA cleavage reactions were investigated using electrophoresis and linear dichroism technique (LD). All four metal complexes effectively cleaved pBR322 super-coiled DNA.
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