ALD00352

Boc-2-methoxy-L-phenylalanine

97%

• Synonym(s): (S)-2-(tert-butoxycarbonylamino)-3-(2-methoxyphenyl)propanoic acid
• Empirical Formula (Hill Notation): C₁₅H₂₁NO₅
• CAS Number: 143415-63-8
• Molecular Weight: 295.33
• MDL number: MFCD01860640
• UNSPSC Code: 12352209
• PubChem Substance ID: 329772655
• NACRES: NA.22

Properties

• Assay: 97%
• form: powder
• reaction suitability: reaction type: Boc solid-phase peptide synthesis; reagent type: ligand; reaction type: C-H Activation
• mp: 157 °C
• application(s): peptide synthesis
• storage temp.: 2-8°C
• SMILES string: OC([C@@H](NC(OC(C)(C)C)=O)CC1=CC=CC=C1OC)=O
• InChI: 1S/C15H21NO5/c1-15(2,3)21-14(19)16-11(13(17)18)9-10-7-5-6-8-12(10)20-4/h5-8,11H,9H2,1-4H3,(H,16,19)(H,17,18)/t11-/m0/s1
• InChI key: QMHKMTAKTUUKEK-NSHDSACASA-N

Description

Application

Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Other Notes

Ligand-Controlled C(sp³)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable