Skip to Content
Merck
All Photos(2)

Documents

709905

Sigma-Aldrich

Fluorene-2-boronic acid

Synonym(s):

9H-Fluoren-2-yl-boronic acid

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
C13H9B(OH)2
CAS Number:
480424-61-1
Molecular Weight:
210.04
MDL number:
MFCD05664106
UNSPSC Code:
12352103
PubChem Substance ID:
329762520
NACRES:
NA.22

form

solid

mp

125-129 °C

SMILES string

OB(O)c1ccc-2c(Cc3ccccc-23)c1

InChI

1S/C13H11BO2/c15-14(16)11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8,15-16H,7H2

InChI key

OHGJAUSHXQCSQX-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

May contain varying amounts of anhydride

Application

Fluorene-2-boronic acid can be used as a substrate in:
  • Copper-catalyzed γ-arylation of carboxamides.
  • Au(I)-catalyzed protodeboronation reactions.
  • Pd-catalyzed C-H monofunctionalization of benzoquinone.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 2

1 of 2

2-Bromofluorene 95%

Sigma-Aldrich

124060

2-Bromofluorene

Fluorene 98%

Sigma-Aldrich

128333

Fluorene

Eric M Woerly et al.
Journal of the American Chemical Society, 132(20), 6941-6943 (2010-05-06)
Stimulated by the substantial challenge of synthesizing the complex and sensitive stereogenic allene-containing core of (-)-peridinin, the first stereocontrolled coupling of haloallenes with boronic acids has been achieved. This new method and the principles that emerged during its development stand
Gold-Catalyzed Proto-and Deuterodeboronation
Barker G, et al.
The Journal of Organic Chemistry, 80(20), 9807-9816 (2015)
Palladium-Catalyzed Direct C-H Functionalization of Benzoquinone
Walker SE, et al.
Angewandte Chemie (International Edition in English), 126(50), 14096-14099 (2014)
Copper-Catalyzed Arylation of Remote C (sp3)- H Bonds in Carboxamides and Sulfonamides
Li Z, et al.
Angewandte Chemie (International Edition in English), 57(40), 13288-13292 (2018)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service