498890
3-Methylbutylzinc bromide solution
0.5 M in THF
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About This Item
Linear Formula:
(CH3)2CHCH2CH2ZnBr
CAS Number:
Molecular Weight:
216.43
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
concentration
0.5 M in THF
density
0.97 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC(C)CC[Zn]Br
InChI
1S/C5H11.BrH.Zn/c1-4-5(2)3;;/h5H,1,4H2,2-3H3;1H;/q;;+1/p-1
InChI key
NCVCJECJAXGYFE-UHFFFAOYSA-M
Application
3-Methylbutylzinc bromide can be used:
- To prepare methyl 4-(3-methylbutanoyl)benzoate, a key starting material for the synthesis of indazole-based glucagon receptor antagonists.
- To synthesize deuterium-labeled azanickelacyclobutane by reacting with deuterium-labeled aziridine and Me4phen/ NiCl2.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react 2
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
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Design, synthesis and structure activity relationships of indazole and indole derivatives as potent glucagon receptor antagonists
Song F, et al.
Bioorganic & Medicinal Chemistry Letters, 29(15), 1974-1980 (2019)
Highly regioselective nickel-catalyzed cross-coupling of N-tosylaziridines and alkylzinc reagents
Jensen KL, et al.
Journal of the American Chemical Society, 136(31), 11145-11152 (2014)
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