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448931

Sigma-Aldrich

Trichloro(1H,1H,2H,2H-perfluorooctyl)silane

97%

Synonym(s):

Trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane, 1H,1H,2H,2H-Perfluorooctyl-trichlorosilane

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About This Item

Linear Formula:
CF3(CF2)5CH2CH2SiCl3
CAS Number:
Molecular Weight:
481.54
Beilstein:
6154526
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

97%

refractive index

n20/D 1.352 (lit.)

bp

192 °C (lit.)

density

1.3 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CC[Si](Cl)(Cl)Cl

InChI

1S/C8H4Cl3F13Si/c9-25(10,11)2-1-3(12,13)4(14,15)5(16,17)6(18,19)7(20,21)8(22,23)24/h1-2H2

InChI key

PISDRBMXQBSCIP-UHFFFAOYSA-N

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General description

Trichloro(1H,1H,2H,2H-perfluorooctyl)silane (PFOCTS) is a chlorosilane that forms a self-assembled monolayer (SAM) on a variety of substrates. It is majorly used to modify the surface with superhydrophobic properties. It is a biocompatible polymer with low surface energy. PFOCTS exhibits anti-fouling properties with high wettability which facilitates the release of different composites from the mold.

Application

PFOCTS is a coupling agent that is used to silanize the substrate for the fabrication of microfluidic devices using soft lithography. It can also be used on silicon base that forms a chemically patterned surface for quantitative analysis of insoluble surfactants in the polymeric matrix. Alumina membranes can be treated with PFOCTS for the formation of surperhydrophobic polyimide (PI) based nanotube arrays.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

188.6 °F - closed cup

Flash Point(C)

87 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of Colloid and Interface Science, 344(2), 541-546 (2010)
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Soluble surfactant spreading on spatially confined thin liquid films
Hanyak M, et al.
Soft Matter, 8(29), 7660-7671 (2012)
Pulsatile micromixing using water-head-driven microfluidic oscillators
Li Z and Kim S
Chemical Engineering Journal, 313(1), 1364-1369 (2017)
Superhydrophobic surfaces fabricated by microstructuring of stainless steel using a femtosecond laser.
Wu B, et al.
Applied Surface Science, 256(1), 61-66 (2009)

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