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Sigma-Aldrich

Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer

greener alternative

95%

Synonym(s):

(1,5-Cyclooctadiene)ruthenium(II) chloride, Ruthenium(II) chloride 1,5-cyclooctadiene complex

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About This Item

Linear Formula:
[Ru(COD)Cl2]n
CAS Number:
Molecular Weight:
280.16 (as monomer)
UNSPSC Code:
12161600
NACRES:
NA.22

Assay

95%

reaction suitability

core: ruthenium
reaction type: solution phase peptide synthesis
reagent type: catalyst

greener alternative product characteristics

Catalysis
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InChI

1S/C8H12.2ClH.Ru/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2

InChI key

DMRVBCXRFYZCPR-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Versatile Ru catalyst precursor. Used with IMes to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.
Versatile ruthenium catalyst precursor. Used with NHC ligand to catalyze greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Articles

We are proud to offer a number of products used in catalytic amidation technology.

We are proud to offer a number of products used in catalytic amidation technology.

We are proud to offer a number of products used in catalytic amidation technology.

We are proud to offer a number of products used in catalytic amidation technology.

Protocols

Acetylene chemistry's versatile applications from organic synthesis to bioorganic chemistry demand efficient synthesis methods.

Acetylene chemistry's versatile applications from organic synthesis to bioorganic chemistry demand efficient synthesis methods.

Acetylene chemistry's versatile applications from organic synthesis to bioorganic chemistry demand efficient synthesis methods.

Acetylene chemistry's versatile applications from organic synthesis to bioorganic chemistry demand efficient synthesis methods.

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