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Sigma-Aldrich

2-Phenylbenzothiazole

97%

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About This Item

Empirical Formula (Hill Notation):
C13H9NS
CAS Number:
Molecular Weight:
211.28
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

mp

111-113 °C (lit.)

SMILES string

c1ccc(cc1)-c2nc3ccccc3s2

InChI

1S/C13H9NS/c1-2-6-10(7-3-1)13-14-11-8-4-5-9-12(11)15-13/h1-9H

InChI key

XBHOUXSGHYZCNH-UHFFFAOYSA-N

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Application

2-Phenylbenzothiazole was used in the synthesis of two novel orange iridium(III) complexes, (bis[2-(biphenyl-3-yl)benzothiazole-N,C2′]iridium(III)(acetylacetonate) and bis[2-(4′-methoxybiphenyl-3-yl)benzothiazole-N,C2′]iridium(III) (acetylacetonate).

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


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Rupam Sarma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 77(1), 126-129 (2010-06-16)
The UV-visible and fluorescence properties of hydroxy substituted benzothiazole derivatives change on interactions with zinc(II), cadmium(II) and mercury(II) ions. The binding of 2-(2'-hydroxyphenyl)benzothiazole is specific to zinc(II) over cadmium(II) and mercury(II). Similar type of interactions of zinc(II), cadmium(II) and mercury(II)
Jun Dai et al.
Dalton transactions (Cambridge, England : 2003), 42(29), 10559-10571 (2013-06-14)
By introducing a phenyl substituent into the meta-site of the phenyl segment of the 2-phenylbenzothiazole ligand, two novel orange iridium(III) complexes, namely, (3Phbt)2Ir(acac) and (3OMePhbt)2Ir(acac), have been synthesized. Compared with their parent compound (bt)2Ir(acac), both of them possess much enhanced
Ravindra M Kumbhare et al.
Bioorganic & medicinal chemistry letters, 22(17), 5424-5427 (2012-08-04)
A new series of isoxazoles and triazoles linked 2-phenyl benzothiazole were synthesized and evaluated for their anticancer activity. These compounds have been tested for their cytotoxicity three cancer cell lines. Among the compounds tested, compound 5d showed good cytotoxicity against
Danjuan Han et al.
Analytica chimica acta, 1074, 98-107 (2019-06-05)
A new cyclometalated iridium complex, [(bt)2Ir(bpy-Fc)]PF6 (bt = 2-phenylbenzothiazole, bpy-Fc = 4-ferrocenecarbonyl hydrazinocarbonyl-4'-methyl- 2,2'-bipyridine) (probe 1) was designed and synthesized for rapid photoluminescent (PL) and electrochemiluminescent (ECL) sensing of hypochlorite (ClO-). Probe 1 exhibits weak PL and ECL emissions attributed to its electron transfer
Stamatia Tzanopoulou et al.
Inorganic chemistry, 45(2), 902-909 (2006-01-18)
The reaction of 2-(2'-pyridyl)benzothiazole, [NN], with the ReO(V)(3+) and TcO(V)(3+) cores in the presence of thiophenols, [S] (RC(6)H(4)SH, R = H, 4-CH(3), 4-OCH(3)), as coligands led to the isolation of hexacoordinated complexes of the MO[NN][S](3) type (M = Re, Tc).

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