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398608

Sigma-Aldrich

Polyphosphoric acid

~105% H3PO4 basis

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About This Item

Linear Formula:
Hn+2PnO3n+1
CAS Number:
EC Number:
MDL number:
UNSPSC Code:
12352106
eCl@ss:
38070203
NACRES:
NA.21

Assay

~105% H3PO4 basis

Quality Level

form

viscous liquid

bp

300 °C (lit.)

mp

16 °C

density

1.9 g/mL at 25 °C

InChI

1S/O5P2.H3O4P/c1-2-7-4-3-6(1)5-7;1-5(2,3)4/h;(H3,1,2,3,4)

InChI key

FVYIVXLIMHNYTD-UHFFFAOYSA-N

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General description

Polyphosphoric acid is a hygroscopic, clear and viscous liquid. It has been synthesized by reacting phosphoric acid with phosphorus (V) oxide. It is a moderately strong mineral acid with a wide range of applications. PPA may be used in bone regeneration by treating titanium (Ti) implants.

Application

Polyphosphoric acid may be used in the following processes:
  • Functionalize mesoporous silica–polymer nanocomposites (SBA/PS).
  • As a catalyst in the synthesis of 3,4-dihydropyrimidin-2-(1H)-ones.
  • As a dehydrating agent and phosphorus source in the synthesis of Si, P co-doped carbon (SiPDC) materials.
  • As a catalyst and absorbent of ammonia during the synthesis of dimethyl carbonate (DMC).
  • As a solvent in the synthesis of hyperbranched polybenzoxazoles (HBPBOs).

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1


Certificates of Analysis (COA)

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Synthesis of hyperbranched polybenzoxazoles and their molecular composites with epoxy resins.
Wu J, et al.
Journal of Applied Polymer Science, 132(18) (2015)
Polyphosphoric Acid
Dodd JH.<BR/>
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Polyphosphoric acid catalyst for the one-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones by grinding under solvent-free conditions.
Zhao Y, et al.
Indian J. Chem. B, 54(1), 139-141 (2015)
Mesoporous silica polymer nanocomposites encapsulated with polyphosphoric acid for the synthesis of ?-amino carbonyl compounds under environmental benign conditions.
Sachdev D, et al.
New. J. Chem., 39(4), 2633-2641 (2015)
Novel tannin-based Si, P co-doped carbon for supercapacitor applications.
Ramasahayam SK, et al.
Journal of Power Sources, 275, 835-844 (2015)

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