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284513

Chlorobenzene

anhydrous, 99.8%

Chlorobenzene
1 of 1 reviewers received a sample product or took part in a promotion
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About This Item

Empirical Formula (Hill Notation):
C6H5Cl
CAS Number:
Molecular Weight:
112.56
UNSPSC Code:
12352101
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-628-5
Beilstein/REAXYS Number:
605632
MDL number:
Assay:
99.8%
Grade:
anhydrous
Bp:
132 °C (lit.)
Vapor pressure:
11.8 mmHg ( 25 °C)
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grade

anhydrous

Quality Segment

vapor density

3.86 (vs air)

vapor pressure

11.8 mmHg ( 25 °C)

assay

99.8%

form

liquid

autoignition temp.

1178 °F

expl. lim.

7.1 %

impurities

<0.005% water

evapn. residue

<0.0005%

refractive index

n20/D 1.524 (lit.)

bp

132 °C (lit.)

mp

−45 °C (lit.)

density

1.106 g/mL at 25 °C (lit.)

SMILES string

Clc1ccccc1

InChI

1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H

InChI key

MVPPADPHJFYWMZ-UHFFFAOYSA-N

Application

Chlorobenzene may be used in the arylation of 2-isobutylthiazole in the presence of palladium (II) acetate-butyldi-1-adamantylphosphine to form 5-phenyl-2-isobutylthiazole. It may also be used as a solvent for the synthesis of rhodium II tetrakis(triphenylacetate) dimer, an efficient rhodium catalyst for nitrene C-H insertion reactions.

Other Notes

The article number 284513-6X1L will be discontinued. Please order the single bottle 284513-1L which is physically identical with the same exact specifications.

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This Item
900521101389319996
assay

99.8%

assay

99.8%

assay

99%

assay

≥99.5%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

grade

anhydrous

grade

ZerO2®

grade

-

grade

ACS reagent

form

liquid

form

liquid

form

liquid

form

liquid

mp

−45 °C (lit.)

mp

−45 °C (lit.)

mp

−45 °C (lit.)

mp

−45 °C (lit.)

expl. lim.

7.1 %

expl. lim.

7.1 %

expl. lim.

7.1 %

expl. lim.

7.1 %


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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

80.6 °F

flash_point_c

27 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi, I have one question related to chlorobenzene solvent. What is the percentage of oxygen contains in this solvent? Best regrads Suraj

    1 answer
    1. There are no oxygen molecules present in this compound. This product is packaged in a Sure/Seal™ bottle which was developed to protect our growing line of air-sensitive reagents from oxygen and moisture. For more information about the Sure/Seal™ system, check the following link: https://www.sigmaaldrich.com/technical-documents/technical-article/chemistry-and-synthesis/organic-reaction-toolbox/sureseal

      Helpful?

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