If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
T61301
Triethyl phosphonoacetate
98%
Synonym(s):
(Diethoxyphosphinyl)acetic acid ethyl ester, Diethyl ethoxycarbonylmethylphosphonate, NSC 13898, NSC 16128, Triethyl carboxymethylphosphonate
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| Size/SKU | Availability | Price |
|---|
About This Item
Quality Segment
assay
98%
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.431 (lit.)
bp
142-145 °C/9 mmHg (lit.)
density
1.13 g/mL at 25 °C (lit.)
SMILES string
CCOC(=O)CP(=O)(OCC)OCC
InChI
1S/C8H17O5P/c1-4-11-8(9)7-14(10,12-5-2)13-6-3/h4-7H2,1-3H3
InChI key
GGUBFICZYGKNTD-UHFFFAOYSA-N
Application
- Horner-Wadsworth-Emmons reactions
- Intramolecular Heck-type cyclization and isomerizations
- Tsuji-Trost type reactions
- Intramolecular aryne-ene reactions
- Synthesis of aldehydes
1 of 1
This Item | |||
|---|---|---|---|
| assay 98% | assay ≥97.0% (GC) | assay 98% | assay 97% |
| reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation | reaction suitability reaction type: C-C Bond Formation |
| Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| refractive index n20/D 1.431 (lit.) | refractive index n20/D 1.431 (lit.), n20/D 1.432 | refractive index n20/D 1.437 (lit.) | refractive index n20/D 1.433 (lit.) |
| bp 142-145 °C/9 mmHg (lit.) | bp 142-145 °C/9 mmHg (lit.) | bp 118 °C/0.85 mmHg (lit.), 265-268 °C (lit.) | bp 127-131 °C/9 mmHg (lit.) |
| density 1.13 g/mL at 25 °C (lit.) | density 1.13 g/mL at 25 °C (lit.) | density 1.125 g/mL at 25 °C (lit.) | density 1.145 g/mL at 25 °C (lit.) |
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 2
flash_point_f
221.0 °F - closed cup
flash_point_c
105 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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