930202

3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride

≥95%, powder

• Synonym(s): 3-(2,6-diisopropylphenyl)-4,5-dimethyl-1-(2,4,6-trimethylbenzyl)-1H-imidazol-3-ium chloride
• Empirical Formula (Hill Notation): C₂₇H₃₇ClN₂
• CAS Number: 1807855-96-4
• Molecular Weight: 425.05
• UNSPSC Code: 12352005
• NACRES: NA.21

Properties

• Product Name: 3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride, ≥95%
• Quality Segment: 100
• assay: ≥95%
• form: powder
• reaction suitability: reagent type: ligand; reaction type: Cross Couplings
• SMILES string: [Cl-].C=1C=C(C(=C(C1)C(C)C)[N+]2=CN(C(=C2C)C)CC=3C(=CC(=CC3C)C)C)C(C)C
• InChI: 1S/C27H37N2.ClH/c1-17(2)24-11-10-12-25(18(3)4)27(24)29-16-28(22(8)23(29)9)15-26-20(6)13-19(5)14-21(26)7;/h10-14,16-18H,15H2,1-9H3;1H/q+1;/p-1
• InChI key: VEFYQHOVUBFLHY-UHFFFAOYSA-M

Description

Application

3-(2,4,6-Trimethylbenzyl)-1-(2,6-diisopropylphenyl)-4,5-dimethylimidazolium chloride is a highly hindered and flexible unsymmetrical NHC ligand for hydrofunctionalization reactions. When combined with a group 11 metal (Cu, Au, Ag), this ligand can be used in hydroelement additions, element-element additions, carbo-element additions, hydrations, hydroaminations, hydroarylations, hyroalkoxylations, hydrocarboxylations, cyclizations, hydrofluorinations, as well as a variety of combined processes using tandem reactions.

Safety Information

• Pictograms: GHS06,GHS05,GHS09
• Signal Word: Danger
• Hazard Codes: H300,H317,H318,H410
• Precautionary Statements: P261 - P273 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable